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261769

8-甲基喹啉

Name: 8-甲基喹啉
Brand: ALDRICH

97%

别名:

邻甲基喹啉

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关于此项目

经验公式（希尔记法）:

C₁₀H₉N

化学文摘社编号:

611-32-5

分子量:

143.19

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24855833

EC Number:

210-264-0

Beilstein/REAXYS Number:

111340

MDL number:

MFCD00006810

Assay:

97%

Form:

liquid

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属性

Quality Level

100

assay

97%

form

liquid

refractive index

n20/D 1.614 (lit.)

bp

143 °C/34 mmHg (lit.)

mp

−80 °C (lit.)

density

1.052 g/mL at 25 °C (lit.)

SMILES string

Cc1cccc2cccnc12

InChI

1S/C10H9N/c1-8-4-2-5-9-6-3-7-11-10(8)9/h2-7H,1H3

InChI key

JRLTTZUODKEYDH-UHFFFAOYSA-N

说明

General description

Tumorigenic potential of 8-methylquinoline has been evaluated in newborn CD-1 mice and Sprague-Dawley rats.

Application

8-Methylquinoline has been used in preparation of osmium chloridophosphine complexes, as quinoline carbene tautomers.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

221.0 °F - closed cup

flash_point_c

105 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

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Palladium-catalyzed fluorination of carbon-hydrogen bonds.

Kami L Hull et al.

Journal of the American Chemical Society, 128(22), 7134-7135 (2006-06-01)

This communication describes the development of a new Pd-catalyzed method for the fluorination of carbon-hydrogen bonds. A key step of these transformations involves palladium-mediated carbon-fluorine coupling-a much sought after, but previously unprecedented, transformation. These reactions were successfully achieved under oxidative

Synthetic routes to N-heterocyclic carbene complexes: pyridine-carbene tautomerizations.

Doris Kunz

Angewandte Chemie (International ed. in English), 46(19), 3405-3408 (2007-04-05)

Pd-catalyzed C-H fluorination with nucleophilic fluoride.

Kate B McMurtrey et al.

Organic letters, 14(16), 4094-4097 (2012-08-01)

The palladium-catalyzed C-H fluorination of 8-methylquinoline derivatives with nucleophilic fluoride is reported. This transformation involves the use of AgF as the fluoride source in combination with a hypervalent iodine oxidant. Both the scope and mechanism of the reaction are discussed.

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全球贸易项目编号

货号	GTIN
261769-5G	04061826107706