264679
2,6,6-三甲基-1-环己烯基乙醛
technical grade, 80%
别名:
β-环高柠檬醛
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关于此项目
经验公式（希尔记法）:
C11H18O
化学文摘社编号:
分子量:
166.26
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
207-454-0
MDL number:
Assay:
80%
Form:
liquid
InChI key
VHTFHZGAMYUZEP-UHFFFAOYSA-N
InChI
1S/C11H18O/c1-9-5-4-7-11(2,3)10(9)6-8-12/h8H,4-7H2,1-3H3
SMILES string
[H]C(=O)CC1=C(C)CCCC1(C)C
grade
technical grade
assay
80%
form
liquid
refractive index
n20/D 1.485 (lit.)
bp
58-59 °C/0.4 mmHg (lit.)
density
0.941 g/mL at 25 °C (lit.)
functional group
aldehyde
Quality Level
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Application
2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde can be used as a starting material to prepare:
It can also be used as a key intermediate to synthesize drimane-related sesquiterpenes and substituted retinoic acid analogs.
- (±)-Aeginetolide by oxidation in the presence of meta-chloroperoxybenzoic acid (m-CPBA).
- (±)-Dihydroactinidiolide (a C11-terpenic lactone) via dehydration of key intermediate aeginetolide.
It can also be used as a key intermediate to synthesize drimane-related sesquiterpenes and substituted retinoic acid analogs.
Other Notes
含有 β-环柠檬醛
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Improved Synthesis of 2, 6, 6-Trimethyl-1-cyclohexene-1-acetaldehyde, A Key Intermediate for Drimane-Related Sesquiterpenes
de Jong JC, et al.
Synthetic Communications, 20(4), 589-596 (1990)
An improved synthesis of (?)-dihydroactinidiolide.
Subbaraju GV, et al.
Tetrahedron Letters, 32(37), 4871-4874 (1991)
Improved Synthesis of 2, 6, 6-Trimethyl-1-cyclohexene-1-acetaldehyde, A Key Intermediate for Drimane-Related Sesquiterpenes.
de Jong JC, et al.
Synthetic Communications, 20(4), 589-596 (1990)
Preparation and biological activity of 13-substituted retinoic acids
Wada A, et al.
Bioorganic & Medicinal Chemistry, 12(14), 3931-3942 (2004)
An improved synthesis of (?)-dihydroactinidiolide
Subbaraju GV, et al.
Tetrahedron Letters, 32(37), 4871-4874 (1991)
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