26475
对甲苯基氯化亚硫代甲酸
≥97.0%
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关于此项目
线性分子式:
ClC(S)OC6H4CH3
化学文摘社编号:
分子量:
186.66
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-333-3
Beilstein/REAXYS Number:
1448986
MDL number:
Assay:
≥97.0%
InChI key
UNCAXIZUVRKBMN-UHFFFAOYSA-N
InChI
1S/C8H7ClOS/c1-6-2-4-7(5-3-6)10-8(9)11/h2-5H,1H3
SMILES string
Cc1ccc(OC(Cl)=S)cc1
assay
≥97.0%
Quality Level
bp
245 °C (lit.), 50 °C/0.2 mmHg (lit.)
density
1.225 g/mL at 25 °C (lit.)
functional group
chloro
storage temp.
2-8°C
Application
O-(p-Tolyl) chlorothionoformate has been used in the synthesis of:
- α-L-2′-deoxythreofuranosyl nucleoside analogs
- alkenes from hindered alcohols
Other Notes
由位阻醇合成烯烃
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Skin Corr. 1B
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
204.8 °F - closed cup
flash_point_c
96 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
H. Gerlach et al.
Helvetica Chimica Acta, 55, 2277-2277 (1972)
A.P. Neary et al.
Journal of the Chemical Society. Chemical Communications, 1090-1090 (1989)
Kiran S Toti et al.
European journal of medicinal chemistry, 46(9), 3704-3713 (2011-06-15)
The synthesis of a series of α-L-2'-deoxythreofuranosyl nucleosides featuring the nucleobases A, T, C and U is described in seven steps from 1,2-O-isopropyledene-α-L-threose, involving a Vorbrüggen coupling and a Barton-McCombie deoxygenation protocol as the key steps. All analogues, including a
H. Gerlach et al.
Journal of the Chemical Society. Chemical Communications, 1215-1215 (1972)
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