270962
双(2-氧代-3-噁唑烷基)次磷酰氯
97%
别名:
BOP-Cl, Phosphoric acid bis(2-oxooxazolidide) chloride
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关于此项目
经验公式（希尔记法）:
C6H8ClN2O5P
化学文摘社编号:
分子量:
254.56
PubChem Substance ID:
UNSPSC Code:
12352100
Beilstein/REAXYS Number:
3654596
MDL number:
assay
97%
mp
191 °C (dec.) (lit.)
SMILES string
ClP(=O)(N1CCOC1=O)N2CCOC2=O
InChI
1S/C6H8ClN2O5P/c7-15(12,8-1-3-13-5(8)10)9-2-4-14-6(9)11/h1-4H2
InChI key
KLDLRDSRCMJKGM-UHFFFAOYSA-N
Application
羧基活化和肽偶联的试剂。
Other Notes
This product has been replaced by 15140-ALDRICH | Bis(2-oxo-3-oxazolidinyl)phosphinic chloride ≥97.0% (AT)
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
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Nonionic surfactants regioselective synthesis of fatty acid esters of alpha- and beta-glucopyranose.
D De Luca et al.
Lipids, 32(5), 559-563 (1997-05-01)
Lipophilic esters of saccharides belong to the family of nonionic surfactants widely employed in pharmaceutical and cosmetics formulations. A very simple method is presented whereby 6-O-esters of alpha- and beta-glucose can be prepared and isolated. Good results have been obtained
H T Le et al.
Bioorganic & medicinal chemistry, 4(12), 2201-2209 (1996-12-01)
BOP-Cl was found to be an efficient coupling reagent for the introduction of thiopeptide bonds on imino acid residues (Pro, Sar). Boc-amino monothioacids were coupled at moderate temperature (0 degree C-RT) with fair yields and with retained optical purity. The
T Miyazawa et al.
International journal of peptide and protein research, 40(1), 49-53 (1992-07-01)
In segment couplings by the mixed anhydride method using isobutyloxycarbonyl chloride, the use of copper(II) chloride as an additive suppressed racemization completely in the same manner as in the carbodiimide method reported previously. This was confirmed by employing a number