273112
(1R,E)-(+)-樟脑醌-3-肟
99%
别名:
(1R,E)-(+)-2,3-Bornanedione 3-oxime, 反式-(1R)-(+)-樟脑醌-3-肟
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关于此项目
经验公式（希尔记法）:
C10H15NO2
化学文摘社编号:
分子量:
181.23
Beilstein:
3200377
MDL编号:
UNSPSC代码:
12352115
PubChem化学物质编号:
NACRES:
NA.22
方案
99%
表单
solid
旋光性
[α]25/D +200°, c = 1 in ethanol
mp
153-156 °C (lit.)
官能团
ketone
oxime
SMILES字符串
[H][C@@]12CC[C@@](C)(C(=O)\C1=N/O)C2(C)C
InChI
1S/C10H15NO2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11-13/h6,13H,4-5H2,1-3H3/b11-7-/t6-,10+/m1/s1
InChI key
YRNPDSREMSMKIY-HAKKTOSXSA-N
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应用
(1R,E)-(+)-Camphorquinone 3-oxime can be used to prepare chiral camphor-oxazoline auxiliary, which is used to blend diastereoselectivity and isomer separability for the efficient synthesis of bicuculline, egenine, corlumine, and corytensine.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves
法规信息
新产品
此项目有
1-Magnesiotetrahydroisoquinolyloxazolines as Chiral Nucleophiles in Stereoselective Additions to Aldehydes: Auxiliary Optimization, Asymmetric Synthesis of (+)-Corlumine,(+)-Bicuculline,(+)-Egenine, and (+)-Corytensine, and Preliminary 13C NMR Studies of 1-Lithio-and 1-Magnesiotetrahydroisoquinolyloxazolines
Gawley RE and Z Pingsheng
The Journal of Organic Chemistry, 61(23), 8103- 8112 (1996)
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