274259
P,P-双(2,2,2-三氟乙基)磷乙酸甲酯
95%
别名:
双(2,2,2-三氟乙基)(甲氧羰基甲基)膦酸酯
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关于此项目
线性分子式:
CH3O2CCH2P(O)(OCH2CF3)2
化学文摘社编号:
分子量:
318.11
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3594044
Assay:
95%
Form:
liquid
InChI
1S/C7H9F6O5P/c1-16-5(14)2-19(15,17-3-6(8,9)10)18-4-7(11,12)13/h2-4H2,1H3
SMILES string
COC(=O)CP(=O)(OCC(F)(F)F)OCC(F)(F)F
InChI key
PVSJXEDBEXYLML-UHFFFAOYSA-N
assay
95%
form
liquid
reaction suitability
reaction type: C-C Bond Formation
Quality Level
density
1.504 g/mL at 25 °C (lit.)
functional group
ester, fluoro, phosphonate
Application
P,P-双(2,2,2-三氟乙基)磷乙酸甲酯可用于：
- 反-六氢茚满和(R)-(+)-umbelactone制备的一步主要合成步骤。
- 使用18-冠醚和双(三甲基硅烷基)氨基钾(KHMDS)，通过醛衍生物的Still–Gennari烯烃化反应制备顺-烯烃酯衍生物。
- 合成(−)-(6S,2′S)-表厚壳桂内酯。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Journal of the Chemical Society. Perkin Transactions 1, 2527-2527 (1992)
Sulfur-mediated intramolecular double Michael-type reaction: synthesis of trans-hydroindanes and mechanism
Ihara M, et al.
Journal of the Chemical Society. Perkin Transactions 1, 19, 2527-2535 (1992)
First stereoselective total synthesis of pectinolide H
Ramesh D, et al.
Tetrahedron Letters, 53(10), 1258-1260 (2012)
Stereoselective total synthesis of (+)-(6R, 2′S)-cryptocaryalactone and (−)-(6S, 2′S)-epi cryptocaryalactone
Sabitha G, et al.
Tetrahedron, 64(44), 10207-10213 (2008)
An expedient synthesis of (R)-(+)-umbelactone
Gibson CL and Handa S
Tetrahedron Asymmetry, 7(5), 1281-1284 (1996)
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