276286
(1R)-(-)-樟脑醌
99%
别名:
(1R)-(-)-2,3-莰烷二酮, 2,3-莰烷二酮
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关于此项目
经验公式（希尔记法）:
C10H14O2
化学文摘社编号:
分子量:
166.22
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2327696
Assay:
99%
Quality Segment
assay
99%
optical activity
[α]20/D −101°, c = 2 in toluene
mp
200-203 °C (lit.)
functional group
ketone
SMILES string
CC1(C)[C@@H]2CC[C@@]1(C)C(=O)C2=O
InChI
1S/C10H14O2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6H,4-5H2,1-3H3/t6-,10+/m1/s1
InChI key
VNQXSTWCDUXYEZ-LDWIPMOCSA-N
Application
(1R)-(−)-Camphorquinone can be used as a chiral starting material for the preparation of:
- α-Hydroxycamphors by selective reduction of keto groups using various vegetables.
- Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies.
- Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents.
- Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Resp. Sens. 1
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves