主要文件

查看所有文档

276286

(1R)-(-)-樟脑醌

Name: (1<I>R</I>)-(-)-樟脑醌
Brand: ALDRICH

99%

别名:

(1R)-(-)-2,3-莰烷二酮, 2,3-莰烷二酮

登录查看组织和合同定价。

选择尺寸

变更视图

关于此项目

经验公式（希尔记法）:

C₁₀H₁₄O₂

化学文摘社编号:

10334-26-6

分子量:

166.22

UNSPSC Code:

12352115

NACRES:

NA.22

PubChem Substance ID:

24856697

MDL number:

MFCD00082863

Beilstein/REAXYS Number:

2327696

Assay:

99%

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

属性

Quality Level

100

assay

99%

optical activity

[α]20/D −101°, c = 2 in toluene

mp

200-203 °C (lit.)

functional group

ketone

SMILES string

CC1(C)[C@@H]2CC[C@@]1(C)C(=O)C2=O

InChI

1S/C10H14O2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6H,4-5H2,1-3H3/t6-,10+/m1/s1

InChI key

VNQXSTWCDUXYEZ-LDWIPMOCSA-N

说明

Application

(1R)-(−)-Camphorquinone can be used as a chiral starting material for the preparation of:

α-Hydroxycamphors by selective reduction of keto groups using various vegetables.
Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies.
Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents.
Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement.

pictograms

GHS08,GHS07

signalword

Danger

hcodes

H302,H334

pcodes

P261 - P264 - P270 - P284 - P301 + P312 - P501

Hazard Classifications

Acute Tox. 4 Oral - Resp. Sens. 1

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

没有发现合适的版本？

如果您需要特殊版本，可通过批号或批次号查找具体证书。

搜索COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Enantioselective transfer aminoallylation: synthesis of optically active homoallylic primary amines.

Masaharu Sugiura et al.

Journal of the American Chemical Society, 128(34), 11038-11039 (2006-08-24)

A camphorquinone-derived chiral homoallylic amine was found to react with various aldehydes via imine formation and asymmetric 2-azonia-Cope rearrangement to give optically active homoallylic primary amines. A practical level of enantioselectivity with high functional group tolerance has been attained in

Stereoselective reduction of ketones by various vegetables

Utsukihara T, et al.

Journal of Molecular Catalysis. B, Enzymatic, 41(3-4), 103-109 (2006)

Synthesis, characterization and antiproliferative studies of the enantiomers of cis-[(1,2-camphordiamine)dichloro]platinum(II) complexes.

Angel M Montaña et al.

Bioorganic & medicinal chemistry, 16(4), 1721-1737 (2007-11-27)

The platinum(II) complex cis-[(1S,2R,3S)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-diamine]dichloroplatinum(II) (1) and its enantiomer (2) have been synthesized and physically and spectroscopically characterized. To obtain the enantiopure complexes the chiral pool approach was applied. The synthetic pathway has four steps, starting from (+/-)-diphenylethylenediamine (DPEDA) (3) and

查看所有相关文献

全球贸易项目编号

货号	GTIN
276286-5G	04061826185476