(1R)-(-)-樟脑醌

Name: (1<I>R</I>)-(-)-樟脑醌
Brand: ALDRICH

99%

别名:

(1R)-(-)-2,3-莰烷二酮, 2,3-莰烷二酮

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About This Item

经验公式（希尔记法）:

C₁₀H₁₄O₂

CAS Number:

10334-26-6

分子量:

166.22

Beilstein:

2327696

MDL编号:

MFCD00082863

UNSPSC代码:

12352115

PubChem化学物质编号:

24856697

NACRES:

NA.22

主要文件

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质量水平

100

方案

99%

旋光性

[α]20/D −101°, c = 2 in toluene

mp

200-203 °C (lit.)

官能团

ketone

SMILES字符串

CC1(C)[C@@H]2CC[C@@]1(C)C(=O)C2=O

InChI

1S/C10H14O2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6H,4-5H2,1-3H3/t6-,10+/m1/s1

InChI key

VNQXSTWCDUXYEZ-LDWIPMOCSA-N

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应用

(1R)-(−)-Camphorquinone can be used as a chiral starting material for the preparation of:

α-Hydroxycamphors by selective reduction of keto groups using various vegetables.
Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies.
Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents.
Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement.