278750
(1R,2S,5R)-(-)-薄荷醇 (S)-对甲苯亚磺酸酯
98%
别名:
(-)-(1R)-薄荷基 (S)-对甲苯亚磺酸酯, (S)-(-)-薄荷基 对甲苯亚磺酸酯
InChI
1S/C17H26O2S/c1-12(2)16-10-7-14(4)11-17(16)19-20(18)15-8-5-13(3)6-9-15/h5-6,8-9,12,14,16-17H,7,10-11H2,1-4H3/t14-,16+,17-,20+/m1/s1
SMILES string
C[C@@H]1CC[C@@H](C(C)C)[C@@H](C1)OS(=O)c2ccc(C)cc2
InChI key
NQICGNSARVCSGJ-ASKNOMKYSA-N
assay
98%
form
solid
optical activity
[α]20/D −195°, c = 2 in acetone
mp
102-104 °C (lit.)
functional group
sulfinic acid
storage temp.
−20°C
General description
(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis.
Application
(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate can react with:
- metal ketimines to form enantiopure sulfinimines
- p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Asymmetric synthesis and properties of sulfinimines (thiooxime S-oxides).
Davis FA, et al.
The Journal of Organic Chemistry, 62(8), 2555-2563 (1997)
Asymmetric synthesis of the antibiotic (+)-thiamphenicol using cis-N-(p-toluenesulfinyl) aziridine 2-carboxylic acids
Davis FA and Zhou P.
Tetrahedron Letters, 35(41), 7525-7528 (1994)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持