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283606

氯化钯(II) 溶液

Name: 氯化钯(II) 溶液
Brand: ALDRICH

5 wt. % in 10 wt. % HCl, liquid

别名:

Dichloropalladium, Palladium dichloride, Palladous chloride

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关于此项目

线性分子式:

PdCl₂

化学文摘社编号:

7647-10-1

分子量:

177.33

UNSPSC Code:

12161600

PubChem Substance ID:

24857119

NACRES:

NA.22

MDL number:

MFCD00003558

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属性

产品名称

氯化钯(II) 溶液, 5 wt. % in 10 wt. % HCl

form

liquid

Quality Level

100

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

concentration

5 wt. % in 10 wt. % HCl

density

1.06 g/mL at 25 °C

SMILES string

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChI key

PIBWKRNGBLPSSY-UHFFFAOYSA-L

说明

General description

氯化钯(II)是钯(II)的代表性盐，作为前体用于制备各种反应的钯催化剂，如 Heck 偶联、Suzuki 偶联、Sonagashira 偶联和 Buchwald-Hartwig 偶联。它也可用作氧化剂。

Application

用于合成含半导体金属的聚合物，其中聚吡咯骨架的构象能量最小并且几乎是平面结构。

pictograms

GHS05,GHS07,GHS09

signalword

Danger

hcodes

H290,H317,H318,H410

pcodes

P234 - P261 - P273 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

flash_point_f

Not applicable

flash_point_c

Not applicable

存储类别

12 - Non Combustible Liquids

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Mathis, M. et al.

Chemistry of Materials, 10, 3568-3568 (1998)

Flexible diphosphine ligands with overall charges of 0, +1, and +2: critical role of the electrostatics in favoring trans over cis coordination.

Yves Canac et al.

Inorganic chemistry, 50(21), 10810-10819 (2011-10-11)

The influence of the formal electrostatic interaction on the cis/trans coordination mode at a PdCl(2) center is investigated in a family of isostructural flexible diphosphine ligands Ph(2)P-X-C(6)H(4)-Y-PPh(2), where X and Y stand for neutral or cationic N,C-imidazolylene linkers. While the

Palladium-catalyzed cyanomethylation of aryl halides through domino Suzuki coupling-isoxazole fragmentation.

Juraj Velcicky et al.

Journal of the American Chemical Society, 133(18), 6948-6951 (2011-04-21)

A one-pot protocol for the cyanomethylation of aryl halides through a palladium-catalyzed reaction with isoxazole-4-boronic acid pinacol ester was developed. Mechanistically, the reaction proceeds through (1) Suzuki coupling, (2) base-induced fragmentation, and (3) deformylation as shown by characterization of all

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全球贸易项目编号

货号	GTIN
283606-50ML	04061826245927