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29162

2-氧环己烷羧酸甲酯

Name: 2-氧环己烷羧酸甲酯
Brand: ALDRICH

technical, ≥90% (GC)

别名:

2-甲氧羰基环己酮, 环己酮-2-羧酸甲酯

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关于此项目

经验公式（希尔记法）:

C₈H₁₂O₃

化学文摘社编号:

41302-34-5

分子量:

156.18

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

57648338

EC Number:

255-306-9

Beilstein/REAXYS Number:

510258

MDL number:

MFCD00077699

Assay:

≥90% (GC)

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属性

grade

technical

Quality Level

100

assay

≥90% (GC)

refractive index

n20/D 1.483

bp

50 °C/0.2 mmHg (lit.)

density

1.10 g/mL at 20 °C (lit.)

SMILES string

COC(=O)C1CCCCC1=O

InChI

1S/C8H12O3/c1-11-8(10)6-4-2-3-5-7(6)9/h6H,2-5H2,1H3

InChI key

JEENWEAPRWGXSG-UHFFFAOYSA-N

说明

Application

Methyl 2-oxocyclohexanecarboxylate has been used in the synthesis of substituted tetrahydrobenzofuran derivatives via reaction with propargylic esters in the presence of palladium catalyst.

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

192.2 °F - closed cup

flash_point_c

89 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Highly diastereoselective synthesis of tetrahydrobenzofuran derivatives by palladium-catalyzed reaction of propargylic esters with substituted ?-dicarbonyl compounds.

Yoshida M, et al.

Tetrahedron, 66(14), 2675-2682 (2010)

Synthesis of ketones from biomass-derived feedstock.

Qinglei Meng et al.

Nature communications, 8, 14190-14190 (2017-02-01)

Cyclohexanone and its derivatives are very important chemicals, which are currently produced mainly by oxidation of cyclohexane or alkylcyclohexane, hydrogenation of phenols, and alkylation of cyclohexanone. Here we report that bromide salt-modified Pd/C in H

全球贸易项目编号

货号	GTIN
29162-50ML	04061836691820
29162-10ML	04061836691813