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294071

甲氧基甲基苯硫醚

Name: 甲氧基甲基苯硫醚
Brand: ALDRICH

97%

别名:

[(甲氧基甲基)硫基]苯

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关于此项目

线性分子式:

C₆H₅SCH₂OCH₃

化学文摘社编号:

13865-50-4

分子量:

154.23

UNSPSC Code:

12352100

PubChem Substance ID:

24857701

MDL number:

MFCD00008496

Assay:

97%

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属性

assay

97%

refractive index

n20/D 1.5632 (lit.)

bp

113-114 °C/18 mmHg (lit.)

density

1.047 g/mL at 25 °C (lit.)

functional group

ether, thioether

SMILES string

COCSc1ccccc1

InChI

1S/C8H10OS/c1-9-7-10-8-5-3-2-4-6-8/h2-6H,7H2,1H3

InChI key

QPXQVNXSQCRWEV-UHFFFAOYSA-N

说明

General description

Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide to methoxymethyl benzenesulfenate has been reported. Methoxymethyl phenyl sulfide undergoes solvent free permanganate oxidation to yield methoxymethyl phenyl sulfone.

Application

Methoxymethyl phenyl sulfide has been used in the preparation of methoxymethyl phenyl sulfoxide.

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

203.0 °F - closed cup

flash_point_c

95 °C - closed cup

ppe

Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

MKBQ8863V

16013KA

04309DY

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Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide. Formation and disproportionation of methoxymethyl benzenesulfenate.

Maricich TJ and Harrington CK.

Journal of the American Chemical Society, 94(14), 5115-5116 (1972)

Asymmetric reduction of racemic sulfoxides by dimethyl sulfoxide reductases from Rhodobacter capsulatus, Escherichia coli and Proteus species.

S P Hanlon et al.

Microbiology (Reading, England), 144 ( Pt 8), 2247-2253 (1998-08-28)

The enantioselective reduction of racemic sulfoxides by dimethyl sulfoxide reductases from Rhodobacter capsulatus, Escherichia coli, Proteus mirabilis and Proteus vulgaris was investigated. Purified dimethyl sulfoxide reductase from Rhodobacter capsulatus catalysed the selective removal of (S)-methyl p-tolyl sulfoxide from a racemic

Solvent free permanganate oxidations.

Shaabani A and Lee DG.

Tetrahedron Letters, 42(34), 5833-5836 (2001)

全球贸易项目编号

货号	GTIN
294071-5G	04061837246883