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294640

(S)-4-苄基-2-噁唑烷酮

Name: (<I>S</I>)-4-苄基-2-噁唑烷酮
Brand: ALDRICH

99%

别名:

(4S)-(-)-4-(Phenylmethyl)-1,3-oxazolidin-2-one, (4S)-4-(Phenylmethyl)-2-oxazolidinone, (4S)-4-benzyl-1,3-oxazolidin-2-one, (S)-(-)-4-benzyl-2-oxazolidinone, (S)-4-benzyloxazolidin-2-one

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关于此项目

经验公式（希尔记法）:

C₁₀H₁₁NO₂

化学文摘社编号:

90719-32-7

分子量:

177.20

UNSPSC Code:

12352005

NACRES:

NA.22

PubChem Substance ID:

24857725

MDL number:

MFCD00064496

Beilstein/REAXYS Number:

3649667

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属性

Quality Level

200

assay

99%

form

solid

optical activity

[α]20/D −63°, c = 1 in chloroform

optical purity

ee: 99% (HPLC)

mp

86-88 °C (lit.)

functional group

phenyl

SMILES string

O=C1N[C@H](CO1)Cc2ccccc2

InChI

1S/C10H11NO2/c12-10-11-9(7-13-10)6-8-4-2-1-3-5-8/h1-5,9H,6-7H2,(H,11,12)/t9-/m0/s1

InChI key

OJOFMLDBXPDXLQ-VIFPVBQESA-N

说明

Application

用于不对称合成 (3R)- 和 (3S)-六氢哒嗪-3-羧酸。

手性助剂，最近用于合成 (S)-雌马酚。用于制备和官能化稳定的手性叶立德。

用于不对称烷化反应的手性助剂。

pictograms

GHS08,GHS07

signalword

Warning

hcodes

H302,H373

pcodes

P260 - P264 - P270 - P301 + P312 - P314 - P501

Hazard Classifications

Acute Tox. 4 Oral - STOT RE 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

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Total synthesis and structural revision of (+)-amphidinolide W.

Arun K Ghosh et al.

Journal of the American Chemical Society, 126(12), 3704-3705 (2004-03-25)

An enantioselective first total syntheis of amphidinolide W (2) and a revision of its C6 absolute stereochemistry (1) are described. Amphidinolide W (1), a 12-membered macrolide isolated from Amphidinium sp., has shown potent antitumor properties against a variety of NCI

Total synthesis of (S)-equol.

Jennifer M Heemstra et al.

Organic letters, 8(24), 5441-5443 (2006-11-17)

The first enantioselective total synthesis of (S)-equol is reported. The described route relies on an Evans alkylation to form the stereocenter and an intramolecular Buchwald etherification to generate the chroman ring. Key features of this method include its brevity, its

Tetrahedron Letters, 33, 7613-7613 (1992)

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全球贸易项目编号

货号	GTIN
294640-5G	04061826601341
294640-25G	04061833546048