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Merck
CN

294845

Sigma-Aldrich

溴甲烷 溶液

2.0 M in diethyl ether

别名:

甲基 溴化物

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关于此项目

经验公式(希尔记法):
CH3Br
化学文摘社编号:
分子量:
94.94
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
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蒸汽压

1420 mmHg ( 20 °C)
3945 mmHg ( 55 °C)

质量水平

浓度

2.0 M in diethyl ether

杂质

<0.005% water

密度

0.83 g/mL at 25 °C

应用

agriculture

储存温度

2-8°C

SMILES字符串

CBr

InChI

1S/CH3Br/c1-2/h1H3

InChI key

GZUXJHMPEANEGY-UHFFFAOYSA-N

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一般描述

Bromomethane solution (methyl bromide) is the most effective soil fumigant for killing plant pests, its use is being phased out because its emissions from soil can lead to stratospheric ozone depletion. The bimolecular nucleophilic substitution (SN2) reaction of methyl bromide and OH- in aqueous solution has been investigated using a multilayered-representation quantum mechanical and molecular mechanics methodology.

包装

Supplied in a Sure/Pac cylinder and has a 1/4-turn bronze ball valve with a female 1/4" NPT outlet thread (Z122661) installed. Before using the cylinder, ensure that the valve is closed, then remove carbon steel plug that seals the outlet valve.

Compatible with the following:For instructions please refer to technical bulletin AL-136: The Aldrich Sure/Pac Cylinder System

法律信息

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Ozone 1 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

靶器官

Central nervous system, Respiratory system

补充剂危害

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

-40.0 °F - closed cup

闪点(°C)

-40 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Richeng Xuan et al.
Environmental science & technology, 44(23), 9080-9085 (2010-11-10)
Despite generally being considered the most effective soil fumigant, methyl bromide (MeBr) use is being phased out because its emissions from soil can lead to stratospheric ozone depletion. However, a large amount is still currently used due to Critical Use
Khristy J Thompson et al.
Toxicological sciences : an official journal of the Society of Toxicology, 120(1), 163-172 (2010-12-24)
Manganese (Mn) is an essential nutrient with potential neurotoxic effects. Mn deposited in the nose is apparently transported to the brain through anterograde axonal transport, bypassing the blood-brain barrier. However, the role of the olfactory epithelial cells in Mn transport
Guy J Hallman et al.
Journal of economic entomology, 104(1), 63-68 (2011-03-17)
Methyl bromide fumigation is widely used as a phytosanitary treatment. Mexican fruit fly, Anastrepha ludens (Loew) (Diptera: Tephritidae), is a quarantine pest of several fruit, including citrus (Citrus spp.), exported from Texas, Mexico, and Central America. Recently, live larvae have
Yulong Xu et al.
The Journal of chemical physics, 137(18), 184501-184501 (2012-11-21)
The bimolecular nucleophilic substitution (S(N)2) reaction of CH(3)Br and OH(-) in aqueous solution was investigated using a multilayered-representation quantum mechanical and molecular mechanics methodology. Reactant complex, transition state, and product complex are identified and characterized in aqueous solution. The potentials
Kathryn Hughes Barry et al.
Cancer causes & control : CCC, 23(6), 807-818 (2012-04-25)
Methyl bromide is a genotoxic soil fumigant with high acute toxicity, but unknown human carcinogenicity. Although many countries have reduced methyl bromide use because of its ozone depleting properties, some uses remain in the United States and other countries, warranting

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