295019
三氯化硼
99.9%
蒸汽密度
4.05 (vs air)
蒸汽压
1128 mmHg ( 20 °C)
2815 mmHg ( 55 °C)
方案
99.9%
反应适用性
reagent type: catalyst
core: boron
沸点
12.5 °C (lit.)
mp
−107 °C (lit.)
SMILES字符串
ClB(Cl)Cl
InChI
1S/BCl3/c2-1(3)4
InChI key
FAQYAMRNWDIXMY-UHFFFAOYSA-N
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应用
用于具有 p 型半导体性质的层状类石墨材料的高温合成。衍生自 BCl3 的高度酸性硼酸氧化铝，可提高 Diels-Alder 反应的区域选择性和非对映立体选择性。
其他说明
推荐使用 Monel 控制阀 Z146978 或 Monel 气流阀 Z562483。
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Press. Gas Compr. Gas - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
2A - Gases
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Faceshields, Gloves, Goggles, multi-purpose combination respirator cartridge (US)
法规信息
新产品
此项目有
McGinnis, M.B. et al.
The Journal of Organic Chemistry, 61, 3496-3496 (1996)
Kawaguchi, M. et al.
Chemistry of Materials, 8, 1197-1197 (1996)
George W Kabalka et al.
The Journal of organic chemistry, 73(7), 2668-2673 (2008-03-06)
A boron trihalide mediated alkyne-aldehyde coupling reaction leading to stereodefined 1,3,5-triaryl-1,5-dihalo-1,4-pentadienes is described. The study led to the discovery of a direct substitution of hydroxyl groups by stereodefined alkenyl moieties using alkenylboron dihalides. During the investigation, it was also discovered
Coordination compounds of boron trichloride; systems with the propyl chlorides.
D R MARTIN et al.
The Journal of physical and colloid chemistry, 51(2), 425-430 (1947-03-01)
Jayaraman Selvakumar et al.
Organic & biomolecular chemistry, 8(18), 4056-4058 (2010-07-29)
Isoindoloisoquinalinone, pyrroloisoquinolinone and benzo[a]quinolizinone units are constructed via intramolecular cyclization of the methoxy substituted N-phenethylimides using BBr(3).
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