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关于此项目
经验公式(希尔记法):
BCl3
化学文摘社编号:
分子量:
117.17
UNSPSC Code:
12352106
PubChem Substance ID:
EC Number:
233-658-4
MDL number:
InChI key
FAQYAMRNWDIXMY-UHFFFAOYSA-N
InChI
1S/BCl3/c2-1(3)4
SMILES string
ClB(Cl)Cl
vapor density
4.05 (vs air)
vapor pressure
1128 mmHg ( 20 °C), 2815 mmHg ( 55 °C)
assay
99.9%
reaction suitability
reagent type: catalyst
core: boron
bp
12.5 °C (lit.)
mp
−107 °C (lit.)
Quality Level
Application
用于具有 p 型半导体性质的层状类石墨材料的高温合成。衍生自 BCl3 的高度酸性硼酸氧化铝,可提高 Diels-Alder 反应的区域选择性和非对映立体选择性。
Other Notes
推荐使用 Monel 控制阀 Z146978 或 Monel 气流阀 Z562483。
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Press. Gas Compr. Gas - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
2A - Gases
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, multi-purpose combination respirator cartridge (US)
法规信息
新产品
此项目有
Kawaguchi, M. et al.
Chemistry of Materials, 8, 1197-1197 (1996)
McGinnis, M.B. et al.
The Journal of Organic Chemistry, 61, 3496-3496 (1996)
Lei Zhang et al.
Journal of combinatorial chemistry, 7(4), 622-626 (2005-07-12)
A novel and efficient microwave-assisted, BCl3-mediated coupling reaction to synthesize salicylamide structures from phenols and isocyanates is described.
Jayaraman Selvakumar et al.
Organic & biomolecular chemistry, 8(18), 4056-4058 (2010-07-29)
Isoindoloisoquinalinone, pyrroloisoquinolinone and benzo[a]quinolizinone units are constructed via intramolecular cyclization of the methoxy substituted N-phenethylimides using BBr(3).
Juan Xie et al.
Carbohydrate research, 340(3), 481-487 (2005-02-01)
Boron trichloride has been found to promote selective deprotection of 1,2- or 1,3-cis oriented secondary benzyl ethers of per-benzylated C-glycosyl derivatives. The reactivity towards BCl(3) follows the order: C-4>or=C-2>C-6>C-3 for C-glucopyranosyl derivatives and C-3>or=C-4>C-6>C-2 for C-galactopyranosyl derivatives. Preparatively useful selective
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