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Merck
CN

295485

溴甲烷

≥99%

别名:

甲基溴

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关于此项目

经验公式(希尔记法):
CH3Br
化学文摘社编号:
分子量:
94.94
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-813-2
Beilstein/REAXYS Number:
1209223
MDL number:
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vapor density

3.3 (20 °C, vs air)

Quality Level

vapor pressure

1420 mmHg ( 20 °C)

assay

≥99%

autoignition temp.

996 °F

expl. lim.

~16 %

bp

4 °C (lit.)

mp

−94 °C (lit.)

solubility

water: soluble

density

3.3 g/mL at 25 °C (lit.)

SMILES string

CBr

InChI

1S/CH3Br/c1-2/h1H3

InChI key

GZUXJHMPEANEGY-UHFFFAOYSA-N

General description

Bromomethane (methyl bromide) is the most effective soil fumigant for killing plant pests, its use is being phased out because its emissions from soil can lead to stratospheric ozone depletion. The bimolecular nucleophilic substitution (S(N)2) reaction of methyl bromide and OH- in aqueous solution has been investigated using a multilayered-representation quantum mechanical and molecular mechanics methodology.

Application

Please view www.aldrich.com/epaods regarding the EPA′s request for application information of Ozone Depleting Substances

Other Notes

推荐使用铜质控制阀 Z146943 或 Z146706 和 Z146714 中的任一铜质调节器。


signalword

Danger

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Irrit. 2 - Muta. 2 - Ozone 1 - Press. Gas Liquefied gas - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

存储类别

2A - Gases

wgk

WGK 3

flash_point_f

<-22.0 °F - liquid

flash_point_c

< -30 °C - liquid

ppe

Eyeshields, Faceshields, Gloves

法规信息

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Lot/Batch Number

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Richeng Xuan et al.
Environmental science & technology, 44(23), 9080-9085 (2010-11-10)
Despite generally being considered the most effective soil fumigant, methyl bromide (MeBr) use is being phased out because its emissions from soil can lead to stratospheric ozone depletion. However, a large amount is still currently used due to Critical Use
Lygia T Budnik et al.
Environmental health : a global access science source, 11, 5-5 (2012-01-31)
Although ozone-depleting methyl bromide was destined for phase-out by 2005, it is still widely applied as a consequence of various critical-use-exemptions and mandatory international regulations aiming to restrict the spread of pests and alien species (e.g. in globalized transport and
Alan V Barak et al.
Journal of economic entomology, 104(1), 69-74 (2011-03-17)
Ash (Fraxinus spp.) logs, infested with fully developed, cold-acclimated larval and prepupal emerald ash borer, Agrilus planipennis Fairmaire (Coleoptera: Buprestidae), were fumigated with methyl bromide (MeBr) at 4.4 and 10.0 degrees C for 24 h. Concentrations X time dosages of