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Merck
CN

295485

溴甲烷

≥99%

别名:

甲基溴

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关于此项目

经验公式(希尔记法):
CH3Br
化学文摘社编号:
分子量:
94.94
Beilstein:
1209223
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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蒸汽密度

3.3 (20 °C, vs air)

质量水平

蒸汽压

1420 mmHg ( 20 °C)

方案

≥99%

自燃温度

996 °F

expl. lim.

~16 %

沸点

4 °C (lit.)

mp

−94 °C (lit.)

溶解性

water: soluble

密度

3.3 g/mL at 25 °C (lit.)

SMILES字符串

CBr

InChI

1S/CH3Br/c1-2/h1H3

InChI key

GZUXJHMPEANEGY-UHFFFAOYSA-N

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一般描述

Bromomethane (methyl bromide) is the most effective soil fumigant for killing plant pests, its use is being phased out because its emissions from soil can lead to stratospheric ozone depletion. The bimolecular nucleophilic substitution (S(N)2) reaction of methyl bromide and OH- in aqueous solution has been investigated using a multilayered-representation quantum mechanical and molecular mechanics methodology.

应用

Please view www.aldrich.com/epaods regarding the EPA′s request for application information of Ozone Depleting Substances

其他说明

推荐使用铜质控制阀 Z146943 或 Z146706 和 Z146714 中的任一铜质调节器。

警示用语:

Danger

危险分类

Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Irrit. 2 - Muta. 2 - Ozone 1 - Press. Gas Liquefied gas - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

靶器官

Central nervous system, Respiratory system

储存分类代码

2A - Gases

WGK

WGK 3

闪点(°F)

<-22.0 °F - liquid

闪点(°C)

< -30 °C - liquid

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

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分析证书(COA)

Lot/Batch Number

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Richeng Xuan et al.
Environmental science & technology, 44(23), 9080-9085 (2010-11-10)
Despite generally being considered the most effective soil fumigant, methyl bromide (MeBr) use is being phased out because its emissions from soil can lead to stratospheric ozone depletion. However, a large amount is still currently used due to Critical Use
Marcus Schortemeyer et al.
Journal of economic entomology, 104(3), 717-731 (2011-07-09)
Following the increasing international phasing out of methyl bromide for quarantine purposes, the development of alternative treatments for timber pests becomes imperative. The international accreditation of new quarantine treatments requires verification standards that give confidence in the effectiveness of a
Alan V Barak et al.
Journal of economic entomology, 104(1), 69-74 (2011-03-17)
Ash (Fraxinus spp.) logs, infested with fully developed, cold-acclimated larval and prepupal emerald ash borer, Agrilus planipennis Fairmaire (Coleoptera: Buprestidae), were fumigated with methyl bromide (MeBr) at 4.4 and 10.0 degrees C for 24 h. Concentrations X time dosages of
Paul E Stromberg et al.
Clinical toxicology (Philadelphia, Pa.), 51(3), 182-185 (2013-03-12)
Methyl bromide is a halogenated aliphatic hydrocarbon that exists as a colorless gas or a volatile liquid. Methyl bromide historically had been used in fire extinguishers but is more commonly used as a gas fumigant for soil-borne diseases and pests.
Lygia T Budnik et al.
Environmental health : a global access science source, 11, 5-5 (2012-01-31)
Although ozone-depleting methyl bromide was destined for phase-out by 2005, it is still widely applied as a consequence of various critical-use-exemptions and mandatory international regulations aiming to restrict the spread of pests and alien species (e.g. in globalized transport and

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