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Merck
CN

295647

Sigma-Aldrich

磷化氢

electronic grade, ≥99.9995%

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线性分子式:
PH3
化学文摘社编号:
分子量:
34.00
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
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等级

electronic grade

蒸汽密度

1.15 (vs air)

方案

≥99.9995%

表单

gas

杂质

<1 ppm Argon (Ar)
<1 ppm Arsine (AsH3)
<1 ppm Carbon dioxide (CO2)
<1 ppm Carbon monoxide (CO)
<1 ppm Methane (CH4)
<1 ppm Nitrogen (N2)
<1 ppm Oxygen (O2)
<1 ppm Water (H2O)

沸点

−87.5 °C (lit.)

转变温度

critical temperature 51.3 °C

应用

agriculture
environmental

SMILES字符串

P

InChI

1S/H3P/h1H3

InChI key

XYFCBTPGUUZFHI-UHFFFAOYSA-N

一般描述

Atomic number of base material: 15 Phosphorus
Phosphine is an organophosphorus compound that can be used as a ligand with electronic and steric properties. It can be incorporated into the semiconductor to tune the crystallinity and composition of the nanocrystals by enhancing their photoconductive properties.

应用

III-V 半导体薄膜前体。还用作结晶硅和无定型硅中的掺杂物。
磷化氢主要用于通过 OMCVD 制造 III-IV 半导体材料以及作为结晶硅和无定型硅中的掺杂物。
Phosphine may be used to modify the n-type single walled carbon nanotubes(SWCNTs) for the development of flexible thermoelectric materials. It may also be used as a catalyst in the preparation of cyclobuteno(60)fullerenes which finds potential applications in n-type organic semiconductor.

其他说明

推荐使用不锈钢调节器 Z527416 或 Z527424。

警示用语:

Danger

危险分类

Acute Tox. 1 Inhalation - Aquatic Acute 1 - Eye Dam. 1 - Flam. Gas 1A - Press. Gas Liquefied gas - Self-heat. 1 - Skin Corr. 1B

储存分类代码

2A - Gases

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, multi-purpose combination respirator cartridge (US)

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Long-Wu Ye et al.
Chemical Society reviews, 37(6), 1140-1152 (2008-05-24)
Nucleophilic phosphine catalysis has proven to be a powerful tool in organic synthesis, which can provide easy access to cyclic, bicyclic or polycyclic carbocycles and heterocycles. Owing to their comparatively strong and readily tunable nucleophilicity, phosphines can be easily tailored
Cyclobuteno (60) fullerenes as Efficient n-Type Organic Semiconductors.
Reboredo S, et al.
Chemistry?A European Journal , 22(38), 13627-13631 (2016)
Systematic conversion of single walled carbon nanotubes into n-type thermoelectric materials by molecular dopants.
Nonoguchi Y, et al.
Scientific Reports, 3(12), 3344-3344 (2013)
Aldimine-directed branched-selective hydroarylation of styrenes.
Pin-Sheng Lee et al.
Angewandte Chemie (International ed. in English), 52(4), 1240-1244 (2012-12-12)
Henri A van Kalkeren et al.
ChemSusChem, 6(9), 1615-1624 (2013-09-17)
The conversion of oxygen-containing compounds is often achieved by the use of phosphorus reagents. The newly formed phosphine oxide bond delivers the enthalpic gain that drives reactions, such as the Wittig, Mitsunobu, and Appel reaction, to completion. However, phosphine oxides

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