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Merck
CN

295647

磷化氢

electronic grade, ≥99.9995%

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关于此项目

线性分子式:
PH3
化学文摘社编号:
分子量:
34.00
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
232-260-8
MDL number:
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grade

electronic grade

vapor density

1.15 (vs air)

assay

≥99.9995%

form

gas

impurities

<1 ppm Argon (Ar), <1 ppm Arsine (AsH3), <1 ppm Carbon dioxide (CO2), <1 ppm Carbon monoxide (CO), <1 ppm Methane (CH4), <1 ppm Nitrogen (N2), <1 ppm Oxygen (O2), <1 ppm Water (H2O)

bp

−87.5 °C (lit.)

transition temp

critical temperature 51.3 °C

application(s)

agriculture
environmental

SMILES string

P

InChI

1S/H3P/h1H3

InChI key

XYFCBTPGUUZFHI-UHFFFAOYSA-N

General description

Phosphine is an organophosphorus compound that can be used as a ligand with electronic and steric properties. It can be incorporated into the semiconductor to tune the crystallinity and composition of the nanocrystals by enhancing their photoconductive properties.
Atomic number of base material: 15 Phosphorus

Application

Phosphine may be used to modify the n-type single walled carbon nanotubes(SWCNTs) for the development of flexible thermoelectric materials. It may also be used as a catalyst in the preparation of cyclobuteno(60)fullerenes which finds potential applications in n-type organic semiconductor.
III-V 半导体薄膜前体。还用作结晶硅和无定型硅中的掺杂物。
磷化氢主要用于通过 OMCVD 制造 III-IV 半导体材料以及作为结晶硅和无定型硅中的掺杂物。

Other Notes

推荐使用不锈钢调节器 Z527416 或 Z527424。


signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Aquatic Acute 1 - Eye Dam. 1 - Flam. Gas 1A - Press. Gas Liquefied gas - Self-heat. 1 - Skin Corr. 1B

存储类别

2A - Gases

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, multi-purpose combination respirator cartridge (US)

法规信息

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Chiral phosphine catalyzed asymmetric Michael addition of oxindoles.
Fangrui Zhong et al.
Angewandte Chemie (International ed. in English), 52(3), 943-947 (2012-12-12)
Phosphine
Hamilton and Hardy's Industrial Toxicology, 1295-1300 (2015)
Phosphine-Initiated Cation Exchange for Precisely Tailoring Composition and Properties of Semiconductor Nanostructures: Old Concept, New Applications.
Gui J, et al.
Angewandte Chemie (International Edition in English), 127(12), 3754-3758 (2015)



全球贸易项目编号

货号GTIN
295647-50G04061833606148
295647-10G04061833606131