assay
95%
form
solid
bp
70 °C/0.5 mmHg (lit.)
mp
32-35 °C (lit.)
SMILES string
O=C1COC2(CCCCC2)O1
InChI
1S/C8H12O3/c9-7-6-10-8(11-7)4-2-1-3-5-8/h1-6H2
InChI key
HBGAMCTZOLJGAS-UHFFFAOYSA-N
Application
1,4-Dioxaspiro[4.5]decan-2-one has been used in the synthesis of L-callipeltose, the deoxyamino sugar of L-callipeltoside A.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
221.0 °F - closed cup
flash_point_c
105 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
D A Evans et al.
Organic letters, 3(20), 3133-3136 (2001-09-28)
[reaction: see text] The L-callipeltose subunit of L-callipeltoside A has been synthesized in 10 steps and 13% overall yield from D-threonine. The key steps are a highly diastereoselective Felkin anti aldol addition to a methyl ketone and a selective methylation