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Merck
CN

297976

三丁基硼烷 溶液

1.0 M in diethyl ether

别名:

TBB, Tributylboron

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关于此项目

线性分子式:
[CH3(CH2)3]3B
化学文摘社编号:
分子量:
182.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
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InChI

1S/C12H27B/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3

SMILES string

CCCCB(CCCC)CCCC

InChI key

CMHHITPYCHHOGT-UHFFFAOYSA-N

reaction suitability

reagent type: reductant

concentration

1.0 M in diethyl ether

density

0.719 g/mL at 25 °C

Application

Reactant for:
  • Addition reactions for synthesis of phenyltrialkylborate salts
  • Boron-based multicomponent reactions for generation of substituted aziridines, oxazolidines, and pyrrolidines
  • Suzuki-Miyaura cross coupling of halopurines with trialkylboranes for the synthesis of adenosine A2A receptor antagonists
  • Multicomponent C-alkylation reactions with aromatic aldimines
  • One-pot alkylation-boration and electrophilic substitution

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system

supp_hazards

存储类别

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 1

flash_point_f

-40.0 °F - closed cup

flash_point_c

-40 °C - closed cup

法规信息

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分析证书(COA)

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