298336
3-(全氟丁酰)-(-)-樟脑
98%
别名:
3-(七氟丁酰)-L-樟脑, 3-七氟丁酰-(-)-樟脑
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关于此项目
经验公式（希尔记法）:
C14H15F7O2
化学文摘社编号:
分子量:
348.26
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2306496
Assay:
98%
InChI
1S/C14H15F7O2/c1-10(2)6-4-5-11(10,3)8(22)7(6)9(23)12(15,16)13(17,18)14(19,20)21/h6-7H,4-5H2,1-3H3/t6-,7?,11+/m0/s1
SMILES string
CC1(C)C2CC[C@]1(C)C(=O)C2C(=O)C(F)(F)C(F)(F)C(F)(F)F
InChI key
PEWOESYEGLBLNR-NSMOOJLNSA-N
assay
98%
optical activity
[α]19/D −123°, c = 2.6 in chloroform
refractive index
n20/D 1.422 (lit.)
density
1.218 g/mL at 25 °C (lit.)
Application
3-(Perfluorobutyryl)-(−)-camphor can be used:
- To prepare mesoporous metal-organic hybrid materials, which are used as catalysts in the asymmetric hetero-Diels-Alder cyclization of Danishefsky′s diene with benzaldehydes.
- As a precursor in the synthesis of chiral tetrakis(β-diketonate) Ln(III) complexes.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
199.4 °F - closed cup
flash_point_c
93 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Screening of rare earth metal grafted MCM-41 silica for asymmetric catalysis.
Gerstberger G and Anwander R.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 44, 303-310 (2001)
Yiji Lin et al.
Dalton transactions (Cambridge, England : 2003), 41(22), 6696-6706 (2012-04-28)
Chiral tetrakis(β-diketonate) Ln(III) complexes Δ-[NaLa(d-hfc)(4)(CH(3)CN)] (1) and Λ-[NaLa(l-hfc)(4) (CH(3)CN)] (2) (d/l-hfc(-) = 3-heptafluo-robutylryl-(+)/(-)-camphorate) are a pair of enantiomers and crystallize in the same Sohncke space group (P2(1)2(1)2(1)) with dodecahedral (DD) geometry. Typically positive and negative exciton splitting patterns around 320
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