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Merck
CN

298425

三丁基硼烷

别名:

TBB, Tributylboron

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线性分子式:
[CH3(CH2)3]3B
化学文摘社编号:
分子量:
182.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
EC Number:
204-554-6
MDL number:
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InChI key

CMHHITPYCHHOGT-UHFFFAOYSA-N

InChI

1S/C12H27B/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3

SMILES string

CCCCB(CCCC)CCCC

reaction suitability

reagent type: reductant

bp

109 °C/20 mmHg (lit.)

density

0.747 g/mL at 25 °C (lit.)

Application

Reactant for:
  • Addition reactions for synthesis of phenyltrialkylborate salts
  • Boron-based multicomponent reactions for generation of substituted aziridines, oxazolidines, and pyrrolidines
  • Suzuki-Miyaura cross coupling of halopurines with trialkylboranes for the synthesis of adenosine A2A receptor antagonists
  • Multicomponent C-alkylation reactions with aromatic aldimines
  • One-pot alkylation-boration and electrophilic substitution

Packaging

Supplied in a Sure/Pac cylinder and has a 1/4-turn bronze ball valve with a female 1/4" NPT outlet thread (Z122661) installed. Before using the cylinder, ensure that the valve is closed, then remove carbon steel plug that seals the outlet valve.

Compatible with the following:
For instructions please refer to technical bulletin AL-136: The Aldrich Sure/Pac Cylinder System

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B

存储类别

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)

法规信息

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分析证书(COA)

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S M Moerlein et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 44(9), 1213-1218 (1993-09-01)
Because [15O]butanol is the radiopharmaceutical of choice for PET studies of cerebral perfusion and neurological activation, we have developed a microprocessor-controlled radiosynthetic system for the preparation of this radiotracer in up to ten batches at a time. An IBM-compatible minicomputer
Tetrahedron Letters, 35, 7201-7201 (1994)
The Journal of Organic Chemistry, 59, 5530-5530 (1994)
Tetrahedron Letters, 33, 3779-3779 (1992)
Yohsuke Taira et al.
Journal of dentistry, 36(8), 595-599 (2008-05-24)
The purpose of the present study was to evaluate the effect of five primers (two sulfur, one phosphate, and two sulfur-phosphate dual-function primers) on the bond strength between a self-curing luting agent and gold-copper-silver (Au-Cu-Ag) alloy. The primers used were

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