跳转至内容
Merck
CN

主要文件

查看所有文档

299685

三氟乙酸钯(II)

97%, solid

别名:

Pd(TFA)2, 三氟乙酸 钯(II) 盐

登录 查看组织和合同定价。

选择尺寸

变更视图

关于此项目

线性分子式:
(CF3COO)2Pd
化学文摘社编号:
42196-31-6
分子量:
332.45
UNSPSC Code:
12161600
PubChem Substance ID:
24858054
NACRES:
NA.22
MDL number:
MFCD00013204
技术服务
需要帮助？我们经验丰富的科学家团队随时乐意为您服务。
让我们为您提供帮助

产品名称

三氟乙酸钯(II), 97%

Quality Level

200

assay

97%

form

solid

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: C-H Activation

mp

~220 °C

SMILES string

FC(F)(F)C(=O)O[Pd]OC(=O)C(F)(F)F

InChI

1S/2C2HF3O2.Pd/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2

InChI key

PBDBXAQKXCXZCJ-UHFFFAOYSA-L

General description

三氟乙酸钯是一种催化剂，用于Suzuki-Miyaura、Heck和Stille交叉偶联反应。

Application

可催化香叶基丙酮和其他烯烃的选择性烯丙基氧化，生成相应的乙酸丙烯酯，而后可转化成酮醇。
钯催化交叉偶联反应应用指南
用于富电子芳酸的温和脱羧反应以及未活化芳烃的直接交叉偶联反应的催化剂。

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ1835
MKCT6736
MKCS4523
MKCQ5496
MKCQ9029

没有发现合适的版本？

如果您需要特殊版本，可通过批号或批次号查找具体证书。

搜索COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Mu-Wang Chen et al.
Organic letters, 12(21), 5075-5077 (2010-10-06)
An enantioselective hydrogenation of simple fluorinated imines has been developed using Pd(OCOCF(3))(2)/(R)-Cl-MeO-BIPHEP as a catalyst, and up to 94% ee was achieved. This method provides an efficient route to enantioenriched fluorinated amines.
Keisuke Kato et al.
Angewandte Chemie (International ed. in English), 48(18), 3326-3328 (2009-02-05)
Boxing clever: Direct conversion of a terminal alkyne group into a beta-methoxyacrylate is realized with the aid of the bis(oxazoline) ligand (box). Acetyl and ketal protecting groups, free hydroxy groups, and acid-sensitive glycosidic bonds are not affected under the reaction
Palladium(II)-Catalyzed Direct ortho-C-H Acylation of Anilides by Oxidative Cross-Coupling with Aldehydes using tert-Butyl Hydroperoxide as Oxidant
Chan C, et al.
Advanced Synthesis & Catalysis, 353, 2999-3006 (2011)
查看所有相关文献

全球贸易项目编号

货号GTIN
299685-1G04061826657621
299685-5G04061826657638