299685
三氟乙酸钯(II)
97%, solid
别名:
Pd(TFA)2, 三氟乙酸 钯(II) 盐
登录 查看组织和合同定价。
选择尺寸
关于此项目
线性分子式:
(CF3COO)2Pd
化学文摘社编号:
分子量:
332.45
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
三氟乙酸钯(II), 97%
SMILES string
FC(F)(F)C(=O)O[Pd]OC(=O)C(F)(F)F
InChI
1S/2C2HF3O2.Pd/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2
InChI key
PBDBXAQKXCXZCJ-UHFFFAOYSA-L
assay
97%
form
solid
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: C-H Activation
mp
~220 °C
Quality Level
正在寻找类似产品? 访问 产品对比指南
Application
可催化香叶基丙酮和其他烯烃的选择性烯丙基氧化，生成相应的乙酸丙烯酯，而后可转化成酮醇。
用于富电子芳酸的温和脱羧反应以及未活化芳烃的直接交叉偶联反应的催化剂。
General description
三氟乙酸钯是一种催化剂，用于Suzuki-Miyaura、Heck和Stille交叉偶联反应。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
John E Bercaw et al.
The Journal of organic chemistry, 73(21), 8654-8657 (2008-09-30)
Molecular oxygen can replace sacrificial olefins as the hydrogen acceptor in the palladium trifluoroacetate catalyzed dehydrogenation of cyclohexene and related cyclic olefins into aromatics. One of the major drawbacks of the homogeneous system is the tendency of the palladium trifluoroacetate
Tetrahedron Letters, 25, 4187-4187 (1984)
David R Stuart et al.
Science (New York, N.Y.), 316(5828), 1172-1175 (2007-05-26)
The industrially important coupling of aromatic compounds has generally required differential prefunctionalization of the arene coupling partners with a halide and an electropositive group. Here we report that palladium, in conjunction with a copper oxidant, can catalyze the cross-coupling of
Joshua S Dickstein et al.
Organic letters, 9(13), 2441-2444 (2007-06-05)
A palladium-catalyzed aromatic decarboxylation reaction has been developed. With electron-rich aromatic acids, the reaction proceeds efficiently under fairly mild conditions in good yields. The method was useful with complex functionalized substrates containing hindered carboxylic acids.
Modular synthesis of 1,2-diamine derivatives by palladium-catalyzed aerobic oxidative cyclization of allylic sulfamides.
Richard I McDonald et al.
Angewandte Chemie (International ed. in English), 49(32), 5529-5532 (2010-06-29)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持