299685
三氟乙酸钯(II)
97%, solid
别名:
Pd(TFA)2, 三氟乙酸 钯(II) 盐
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关于此项目
线性分子式:
(CF3COO)2Pd
化学文摘社编号:
分子量:
332.45
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
三氟乙酸钯(II), 97%
Quality Segment
assay
97%
form
solid
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: C-H Activation
mp
~220 °C
SMILES string
FC(F)(F)C(=O)O[Pd]OC(=O)C(F)(F)F
InChI
1S/2C2HF3O2.Pd/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2
InChI key
PBDBXAQKXCXZCJ-UHFFFAOYSA-L
General description
三氟乙酸钯是一种催化剂，用于Suzuki-Miyaura、Heck和Stille交叉偶联反应。
Application
可催化香叶基丙酮和其他烯烃的选择性烯丙基氧化，生成相应的乙酸丙烯酯，而后可转化成酮醇。
用于富电子芳酸的温和脱羧反应以及未活化芳烃的直接交叉偶联反应的催化剂。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves