300373
2,3-二溴丙酰氯
97%
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关于此项目
线性分子式:
BrCH2CHBrCOCl
化学文摘社编号:
分子量:
250.32
EC Number:
242-575-2
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1749801
MDL number:
Assay:
97%
Form:
liquid
InChI key
HWKWYDXHMQQDQJ-UHFFFAOYSA-N
InChI
1S/C3H3Br2ClO/c4-1-2(5)3(6)7/h2H,1H2
SMILES string
ClC(=O)C(Br)CBr
assay
97%
form
liquid
refractive index
n20/D 1.542 (lit.)
bp
191-193 °C (lit.)
density
2.181 g/mL at 25 °C (lit.)
Application
2,3-Dibromopropionyl chloride was used in synthesis of:
- series of 2,3-diaminopropionanilides
- enantiomers of 1,4-dideoxy-1,4-iminolyxitol and 1,4-dideoxy-1,4-iminoribitol
- acromelic acid A
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
150.8 °F - closed cup
flash_point_c
66 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Concise enantioselective synthesis of acromelic acid A.
Takano S, et al.
Journal of the American Chemical Society, 109(18), 5523-5524 (1987)
P A Tenthorey et al.
Journal of medicinal chemistry, 24(9), 1059-1063 (1981-09-01)
A series of 2,3-diaminopropionanilides was synthesized by acylation of mono- and disubstituted aniline derivatives with 2,3-dibromopropionyl chloride and subsequent amination with the appropriate secondary amines. The target compounds were evaluated in mice for antiarrhythmic efficacy against chloroform-induced tachycardia and for
Chiral synthesis of both enantiomers of 1, 4-dideoxy-1, 4-immolyxitol and 1, 4-dideoxy-1, 4-iminoribitol.
Takano S, et al.
Tetrahedron Asymmetry, 3(6), 681-684 (1992)
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