301140
(R)-(-)-六氢扁桃酸
98%, optical purity ee: 99% (GLC)
别名:
(R)-(-)-环己基羟基乙酸
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关于此项目
线性分子式:
C6H11CH(OH)CO2H
化学文摘社编号:
分子量:
158.19
Beilstein:
3196809
MDL编号:
UNSPSC代码:
51113400
PubChem化学物质编号:
NACRES:
NA.22
方案
98%
旋光性
[α]18/D −23°, c = 1 in acetic acid
光学纯度
ee: 99% (GLC)
mp
127-129 °C (lit.)
官能团
carboxylic acid
hydroxyl
SMILES字符串
O[C@H](C1CCCCC1)C(O)=O
InChI
1S/C8H14O3/c9-7(8(10)11)6-4-2-1-3-5-6/h6-7,9H,1-5H2,(H,10,11)/t7-/m1/s1
InChI key
RRDPWAPIJGSANI-SSDOTTSWSA-N
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应用
(R)-(−)-Hexahydromandelic acid can be used:
- As an intermediate in the synthesis of antimycobacterial compound pyridomycin analogs.
- As a model α-hydroxy acid compound in the chirality sensing studies of organic probes using circular dichroism technique.
- As a starting material in the synthesis of chiral ionic liquids, which are applicable as chiral solvents in asymmetric synthesis and as chiral stationary phases in chromatographic separations.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Synthesis and Structure-Activity Relationship Studies of C2-Modified Analogs of the Antimycobacterial Natural Product Pyridomycin
Kienle M, et al.
Journal of medicinal chemistry, 63(3), 1105-1131 (2020)
Chiral ionic liquids: synthesis, properties, and enantiomeric recognition
Yu S, et al.
The Journal of Organic Chemistry, 73(7), 2576-2591 (2008)
Chirality sensing of amines, diamines, amino acids, amino alcohols, and ?-hydroxy acids with a single probe
Bentley KW, et al.
Journal of the American Chemical Society, 135(48), 18052-18055 (2013)
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