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Merck
CN

301868

Sigma-Aldrich

4,7-菲咯啉

98%

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关于此项目

经验公式(希尔记法):
C12H8N2
化学文摘社编号:
分子量:
180.21
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

98%

mp

172-174 °C (lit.)

SMILES字符串

c1cnc2ccc3ncccc3c2c1

InChI

1S/C12H8N2/c1-3-9-10-4-2-8-14-12(10)6-5-11(9)13-7-1/h1-8H

InChI key

DATYUTWESAKQQM-UHFFFAOYSA-N

一般描述

4,7-Phenanthroline reacts with ruthenium carbonyl to yield cyclometalated derivatives.

应用

4,7-Phenanthroline was used in preparation of:
  • cyclic tetranuclear half-sandwich ruthenium(II) complexes
  • positively charged homochiral cyclic trinuclear metallacalix[3]arene species

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Javier A Cabeza et al.
Dalton transactions (Cambridge, England : 2003), 41(24), 7249-7257 (2012-05-10)
The reactions of [Ru(3)(CO)(12)] with four aromatic diazines have been studied in THF at reflux temperature. With phthalazine (L(1)), the compound [Ru(3)(μ-κ(2)N(2)N(3)-L(1))(μ-CO)(3)(CO)(7)] (1), which contains an intact phthalazine ligand in an axial position bridging an Ru-Ru edge through both N
H Olsen et al.
Environmental health perspectives, 102(5), 454-458 (1994-05-01)
This study examined the changes in cellular glucose uptake induced by 2,3,7,8 tetrachlorodibenzo-p-dioxin (TCDD) as measured by quantification of intracellular radioactivity in the NIH 3T3 L1 preadipocyte cell line after a 30-minute incubation with the non-metabolizable radioactive analogue of glucose
H Ashida et al.
Journal of biochemical toxicology, 11(6), 269-278 (1996-01-01)
The effect of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) on lipid peroxidation, 3H-Me-glucose (3H-Me-glu), and 14C-dehydroascorbic acid (14C-DHA) uptakes were studied in adipose tissue of male guinea pig. Under in vitro test conditions, using isolated adipose tissue in a culture medium (explant culture), TCDD
E Enan et al.
Reproductive toxicology (Elmsford, N.Y.), 10(3), 191-198 (1996-05-01)
This study examined the changes in cellular glucose uptake, cAMP-dependent protein kinase (PKA), and progesterone production induced by 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) in human luteinizing granulosa cells (LGCs) in culture. The role of Ah receptor on TCDD-mediated toxicity in human LGCs was
Bennett J D Datu et al.
Veterinary parasitology, 159(2), 139-148 (2008-12-05)
The exit from dauer in the free-living nematode Caenorhabditis elegans is under the control of a single amphidial neuron (ASJ) of the insulin-like signalling pathway. Mutations of this pathway have the ability to suppress entry into the dauer stage. It

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