302163
(R)-(-)-1-苯基-1,2-乙二醇
99%
别名:
(-)-苯乙二醇, (R)-(-)-苯基乙二醇
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关于此项目
线性分子式:
HOCH2CH(C6H5)OH
化学文摘社编号:
分子量:
138.16
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2355547
Assay:
99%
InChI
1S/C8H10O2/c9-6-8(10)7-4-2-1-3-5-7/h1-5,8-10H,6H2/t8-/m0/s1
SMILES string
OC[C@H](O)c1ccccc1
InChI key
PWMWNFMRSKOCEY-QMMMGPOBSA-N
assay
99%
optical activity
[α]20/D −69°, c = 1 in chloroform
bp
272-274 °C (lit.)
mp
64-67 °C (lit.)
functional group
hydroxyl, phenyl
Quality Level
Application
合成不对称氢化反应的手性膦催化剂时所用的中间体。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
J. Chem. Soc. Perkin Trans. II, 489-489 (1982)
The Journal of Organic Chemistry, 44, 1729-1729 (1979)
Yao Nie et al.
Organic & biomolecular chemistry, 9(11), 4070-4078 (2011-04-21)
The application of biocatalysis to the synthesis of chiral molecules is one of the greenest technologies for the replacement of chemical routes due to its environmentally benign reaction conditions and unparalleled chemo-, regio- and stereoselectivities. We have been interested in
Yawei Geng et al.
Wei sheng wu xue bao = Acta microbiologica Sinica, 50(1), 60-66 (2010-03-30)
A novel (S)-specific carbonyl reductase gene (scr II) was cloned from the genome of Candida parapsilosis CCTCC M203011, and its catalytic function for the biotransformation of chiral alcohol was verified. The possible carbonyl reductase gene scr II was amplified by
Hee Sook Kim et al.
Biotechnology letters, 30(1), 127-133 (2007-08-01)
Enantio-convergent hydrolysis of racemic styrene oxides was achieved to prepare enantiopure (R)-phenyl-1,2-ethanediol by using two recombinant epoxide hydrolases (EHs) of a bacterium, Caulobacter crescentus, and a marine fish, Mugil cephalus. The recombinant C. crescentus EH primarily attacked the benzylic carbon
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