302163
(R)-(-)-1-苯基-1,2-乙二醇
99%
别名:
(-)-苯乙二醇, (R)-(-)-苯基乙二醇
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关于此项目
线性分子式:
HOCH2CH(C6H5)OH
CAS Number:
分子量:
138.16
Beilstein:
2355547
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
99%
旋光性
[α]20/D −69°, c = 1 in chloroform
沸点
272-274 °C (lit.)
mp
64-67 °C (lit.)
官能团
hydroxyl
phenyl
SMILES字符串
OC[C@H](O)c1ccccc1
InChI
1S/C8H10O2/c9-6-8(10)7-4-2-1-3-5-7/h1-5,8-10H,6H2/t8-/m0/s1
InChI key
PWMWNFMRSKOCEY-QMMMGPOBSA-N
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应用
合成不对称氢化反应的手性膦催化剂时所用的中间体。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
J. Chem. Soc. Perkin Trans. II, 489-489 (1982)
The Journal of Organic Chemistry, 44, 1729-1729 (1979)
Qingsen Hu et al.
Bioresource technology, 101(22), 8502-8508 (2010-07-16)
Saccharomyces cerevisiae JUC15 was successfully obtained by target reaction-oriented screening, which reduced 2-hydroxy-1-phenylethanone (HPE) to (R)-phenyl-1,2-ethanediol ((R)-PED) of excellent enantiomeric excess (e.e. >99.9%). There was no significant decrease in the yield and optical purity of (R)-PED when the free cells
Y Nie et al.
Letters in applied microbiology, 44(5), 555-562 (2007-04-25)
To purify and characterize the (R)-specific carbonyl reductase from Candida parapsilosis; to compare the enzyme with other stereospecific oxidoreductases; and to develop an available procedure producing optically active (R)-1-phenyl-1,2-ethanediol (PED). An (R)-specific carbonyl reductase was found and purified from C.
Yawei Geng et al.
Wei sheng wu xue bao = Acta microbiologica Sinica, 50(1), 60-66 (2010-03-30)
A novel (S)-specific carbonyl reductase gene (scr II) was cloned from the genome of Candida parapsilosis CCTCC M203011, and its catalytic function for the biotransformation of chiral alcohol was verified. The possible carbonyl reductase gene scr II was amplified by
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