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302589

2-甲基间苯二酚

Name: 2-甲基间苯二酚
Brand: ALDRICH

98%

别名:

2,6-二羟基甲苯

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关于此项目

线性分子式:

CH₃C₆H₃(OH)₂

化学文摘社编号:

608-25-3

分子量:

124.14

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24858264

EC Number:

210-155-8

Beilstein/REAXYS Number:

2042177

MDL number:

MFCD00002271

Assay:

98%

Form:

solid

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属性

assay

98%

form

solid

bp

264 °C (lit.)

mp

114-120 °C (lit.)

SMILES string

Cc1c(O)cccc1O

InChI

1S/C7H8O2/c1-5-6(8)3-2-4-7(5)9/h2-4,8-9H,1H3

InChI key

ZTMADXFOCUXMJE-UHFFFAOYSA-N

说明

General description

研究了 2-甲基间苯二酚与 2-烯烃的反应，以考察间二酚对脂质氧化过程中形成的 2-烯烃的清除能力。

Application

2-甲基间苯二酚用于合成：

5-溴-2-羟基苯基杯[4]-2-甲基间苯二酚
三吡喃类似物
新型芳香族苯并卟啉系列

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pictograms

GHS06,GHS05,GHS09

signalword

Danger

hcodes

H301,H317,H318,H400

pcodes

P261 - P273 - P280 - P301 + P310 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Sens. 1B

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

275.0 °F - closed cup

flash_point_c

135 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Preparation of tripyrrane analogues from resorcinol and 2-methylresorcinol for applications in the synthesis of new benziporphyrin systems.

Kae Miyake et al.

Chemical communications (Cambridge, England), (2)(2), 178-179 (2004-01-23)

Acid catalyzed condensation of resorcinol or 2-methylresorcinol with 2 equiv. of an acetoxymethylpyrrole gave bis(pyrrolylmethyl)benzene derivatives in moderate yields; these afforded a series of novel aromatic benziporphyrins using the MacDonald "3 + 1" methodology.

Synthesis, characterization, X-ray structure and biological activities of C-5-bromo-2-hydroxyphenylcalix[4]-2-methyl resorcinarene.

Hamza M Abosadiya et al.

Molecules (Basel, Switzerland), 18(11), 13369-13384 (2013-11-01)

C-5-bromo-2-hydroxyphenylcalix[4]-2-methylresorcinarene (I) was synthesized by cyclocondensation of 5-bromo-2-hydroxybenzaldehyde and 2-methylresorcinol in the presence of concentrated HCl. Compound I was characterized by infrared and nuclear magnetic resonance spectroscopic data. X-ray analysis showed that this compound crystallized in a triclinic system with

Synthesis of a series of aromatic benziporphyrins and heteroanalogues via tripyrrane-like intermediates derived from resorcinol and 2-methylresorcinol.

Timothy D Lash et al.

The Journal of organic chemistry, 76(15), 6295-6308 (2011-06-23)

Tripyrrane analogues were prepared by reacting resorcinol or 2-methylresorcinol with 2 equiv of an acetoxymethylpyrrole in the presence of p-toluenesulfonic acid and calcium chloride. Following removal of the benzyl ester protective groups, the resorcinol-derived benzitripyrrane was reacted with a pyrrole

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全球贸易项目编号

货号	GTIN
302589-100G	04061826665930
302589-25G	04061826665947