方案
98%
表单
solid
沸点
264 °C (lit.)
mp
114-120 °C (lit.)
SMILES字符串
Cc1c(O)cccc1O
InChI
1S/C7H8O2/c1-5-6(8)3-2-4-7(5)9/h2-4,8-9H,1H3
InChI key
ZTMADXFOCUXMJE-UHFFFAOYSA-N
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一般描述
研究了 2-甲基间苯二酚与 2-烯烃的反应，以考察 间二酚对脂质氧化过程中形成的 2-烯烃的清除能力。
应用
2-甲基间苯二酚用于合成：
- 5-溴-2-羟基苯基杯[4]-2-甲基间苯二酚
- 三吡喃类似物
- 新型芳香族苯并卟啉系列
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Sens. 1B
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
275.0 °F - closed cup
闪点(°C)
135 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Kae Miyake et al.
Chemical communications (Cambridge, England), (2)(2), 178-179 (2004-01-23)
Acid catalyzed condensation of resorcinol or 2-methylresorcinol with 2 equiv. of an acetoxymethylpyrrole gave bis(pyrrolylmethyl)benzene derivatives in moderate yields; these afforded a series of novel aromatic benziporphyrins using the MacDonald "3 + 1" methodology.
Hamza M Abosadiya et al.
Molecules (Basel, Switzerland), 18(11), 13369-13384 (2013-11-01)
C-5-bromo-2-hydroxyphenylcalix[4]-2-methylresorcinarene (I) was synthesized by cyclocondensation of 5-bromo-2-hydroxybenzaldehyde and 2-methylresorcinol in the presence of concentrated HCl. Compound I was characterized by infrared and nuclear magnetic resonance spectroscopic data. X-ray analysis showed that this compound crystallized in a triclinic system with
Francisco J Hidalgo et al.
Food chemistry, 160, 118-126 (2014-05-07)
The reaction between m-diphenols (resorcinol, 2-methylresorcinol, 2,5-dimethylresorcinol, 3-methylphenol, orcinol, and phloroglucinol) and 2-alkenals (2-pentenal and 2-octenal) was studied in an attempt to understand the chemical pathways involved in the scavenging ability of m-diphenols for the 2-alkenals produced as a consequence
Timothy D Lash et al.
The Journal of organic chemistry, 76(15), 6295-6308 (2011-06-23)
Tripyrrane analogues were prepared by reacting resorcinol or 2-methylresorcinol with 2 equiv of an acetoxymethylpyrrole in the presence of p-toluenesulfonic acid and calcium chloride. Following removal of the benzyl ester protective groups, the resorcinol-derived benzitripyrrane was reacted with a pyrrole
O K Davydova et al.
Mikrobiologiia, 75(5), 662-669 (2006-11-10)
The fact of long-term preservation of the physicochemical properties of DNA molecules in aqueous solutions in complexes with methylresorcinol, hexylresorcinol, and tyrosol, the chemical analogues of microbial autoregulators (d1 factors) from the group of alkylhydroxybenzenes (AOB), was established. Compared to
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