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Merck
CN

302589

Sigma-Aldrich

2-甲基间苯二酚

98%

别名:

2,6-二羟基甲苯

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关于此项目

线性分子式:
CH3C6H3(OH)2
化学文摘社编号:
分子量:
124.14
Beilstein:
2042177
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

98%

表单

solid

沸点

264 °C (lit.)

mp

114-120 °C (lit.)

SMILES字符串

Cc1c(O)cccc1O

InChI

1S/C7H8O2/c1-5-6(8)3-2-4-7(5)9/h2-4,8-9H,1H3

InChI key

ZTMADXFOCUXMJE-UHFFFAOYSA-N

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一般描述

研究了 2-甲基间苯二酚与 2-烯烃的反应,以考察 二酚对脂质氧化过程中形成的 2-烯烃的清除能力。

应用

2-甲基间苯二酚用于合成:
  • 5-溴-2-羟基苯基杯[4]-2-甲基间苯二酚
  • 三吡喃类似物
  • 新型芳香族苯并卟啉系列

警示用语:

Danger

危险分类

Acute Tox. 3 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Sens. 1B

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

275.0 °F - closed cup

闪点(°C)

135 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Hamza M Abosadiya et al.
Molecules (Basel, Switzerland), 18(11), 13369-13384 (2013-11-01)
C-5-bromo-2-hydroxyphenylcalix[4]-2-methylresorcinarene (I) was synthesized by cyclocondensation of 5-bromo-2-hydroxybenzaldehyde and 2-methylresorcinol in the presence of concentrated HCl. Compound I was characterized by infrared and nuclear magnetic resonance spectroscopic data. X-ray analysis showed that this compound crystallized in a triclinic system with
Kae Miyake et al.
Chemical communications (Cambridge, England), (2)(2), 178-179 (2004-01-23)
Acid catalyzed condensation of resorcinol or 2-methylresorcinol with 2 equiv. of an acetoxymethylpyrrole gave bis(pyrrolylmethyl)benzene derivatives in moderate yields; these afforded a series of novel aromatic benziporphyrins using the MacDonald "3 + 1" methodology.
Francisco J Hidalgo et al.
Food chemistry, 160, 118-126 (2014-05-07)
The reaction between m-diphenols (resorcinol, 2-methylresorcinol, 2,5-dimethylresorcinol, 3-methylphenol, orcinol, and phloroglucinol) and 2-alkenals (2-pentenal and 2-octenal) was studied in an attempt to understand the chemical pathways involved in the scavenging ability of m-diphenols for the 2-alkenals produced as a consequence
Timothy D Lash et al.
The Journal of organic chemistry, 76(15), 6295-6308 (2011-06-23)
Tripyrrane analogues were prepared by reacting resorcinol or 2-methylresorcinol with 2 equiv of an acetoxymethylpyrrole in the presence of p-toluenesulfonic acid and calcium chloride. Following removal of the benzyl ester protective groups, the resorcinol-derived benzitripyrrane was reacted with a pyrrole
T A Re et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 7(2), 287-292 (1986-08-01)
2-methylresorcinol (2-MR) was administered to groups of 40 male and 35 female Sprague-Dawley rats by admixture with diets at levels of 0.1, 0.4, and 1.5% for periods up to 6 months. Methemoglobin levels were determined after 6 weeks. After 90

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