302775
(R)-(-)-2-甲氧基-2-苯乙醇
98%
别名:
(-)-β-甲氧基苯乙醇
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关于此项目
线性分子式:
C6H5CH(OCH3)CH2OH
化学文摘社编号:
分子量:
152.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352112
MDL number:
产品名称
(R)-(-)-2-甲氧基-2-苯乙醇, 98%
InChI
1S/C9H12O2/c1-11-9(7-10)8-5-3-2-4-6-8/h2-6,9-10H,7H2,1H3/t9-/m0/s1
SMILES string
CO[C@@H](CO)c1ccccc1
InChI key
JDTUPLBMGDDPJS-VIFPVBQESA-N
assay
98%
form
liquid
optical activity
[α]20/D −133°, c = 1 in acetone
optical purity
ee: 99% (GLC)
refractive index
n20/D 1.52 (lit.)
bp
65 °C/0.1 mmHg (lit.)
density
1.05 g/mL at 25 °C (lit.)
functional group
ether
hydroxyl
phenyl
Application
(R)-(-)-2-Methoxy-2-phenylethanol can be employed as a precursor to prepare:
- (−)-3-[(2R)-2-Methoxy-2-phenylethoxy]phenol, a key intermediate for the synthesis of C4-symmetric tetraalkoxy[4]resorcinarenes using boron trifluoride catalyst.
- N-substituent of the 6,7-benzomorphan scaffold that is used as a potent opioid receptor agonist.
- Sodium methoxyphenylethoxide (Na-MPE), which is used as an oxy-initiator in the anionic polymerization of n-hexyl isocyanate.
signalword
Warning
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
208.4 °F - closed cup
flash_point_c
98 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
(2S)-N-2-methoxy-2-phenylethyl-6, 7-benzomorphan compound (2S-LP2): Discovery of a biased mu/delta opioid receptor agonist
Pasquinucci L, et al.
European Journal of Medicinal Chemistry, 168(27), 189-198 (2019)
Effects of different reactive oxyanionic initiators on the anionic polymerizaition of n-hexyl isocyanate.
Min J, et al.
Macromolecules, 44(9), 3211-3216 (2011)
The Diastereoselective Formation of Tetraalkoxy [4] resorcinarenes Derived from (-)-(2R)-2-Methoxy-2-phenylethanol and Proof of Absolute Configurations
Bulman PPC, et al.
European Journal of Organic Chemistry, 2011(27), 5347-5354 (2011)
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