306797
(S)-(-)-2-氯丙酸
99%
别名:
(S)-(-)-2-Chloropropanoic acid, L-α-氯丙酸
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关于此项目
线性分子式:
CH3CH(Cl)CO2H
化学文摘社编号:
分子量:
108.52
EC Number:
411-150-5
UNSPSC Code:
12352101
PubChem Substance ID:
Beilstein/REAXYS Number:
1720257
MDL number:
Assay:
99%
Form:
liquid
InChI key
GAWAYYRQGQZKCR-REOHCLBHSA-N
InChI
1S/C3H5ClO2/c1-2(4)3(5)6/h2H,1H3,(H,5,6)/t2-/m0/s1
SMILES string
C[C@H](Cl)C(O)=O
assay
99%
form
liquid
optical activity
[α]25/D −14°, neat
refractive index
n20/D 1.4347 (lit.)
bp
77 °C/10 mmHg (lit.)
density
1.249 g/mL at 25 °C (lit.)
Application
(S)-(-)-2-氯丙酸可用于制备(S)-(-)-2-氯丙酰氯 和 DOTMA ([αR*(αR*,α′R*,α”R*,α”′R*)]-(α,α′,α”,α”′)-四甲基-1,4,7,10-四氮杂环十二烷-1,4,7,10-四乙酸)配体。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
222.8 °F - closed cup
flash_point_c
106 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
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Aime S, et al.
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Synthesis of optically pure. alpha.-alkylated. alpha.-amino acids and a single-step method for enantiomeric excess determination.
Kruizinga WH, et al.
The Journal of Organic Chemistry, 53(8) (1988)
Gábor Bazsó et al.
The journal of physical chemistry. A, 116(20), 4823-4832 (2012-05-05)
Former assignments of the matrix-isolation infrared (MI-IR) spectrum of 2-chloropropionic acid are revised with the help of near-infrared (NIR) laser irradiation induced change in conformer ratios. This method allows not only the unambiguous assignment of each band in the MI-IR
E A Lock et al.
Toxicology, 123(1-2), 41-51 (1997-11-05)
Administration of a single oral dose of 750 mg/kg L-2-chloropropionic acid (L-CPA) to rats produces marked necrosis to the granule cell layer of the cerebellum by 48 h after dosing. Associated with the neuropathology the rats show locomotor impairment and
Timothy P Higgins et al.
Biodegradation, 16(5), 485-492 (2005-05-04)
We previously reported the presence of both haloalcohol and haloalkanoate dehalogenase activity in the Agrobacterium sp. strain NHG3. The versatile nature of the organism led us to further characterise the genetic basis of these dehalogenation activities. Cloning and sequencing of
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