307408
二异丙基酰胺锂单四氢呋喃 溶液
1.5 M in cyclohexane
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关于此项目
经验公式（希尔记法）:
C10H22LiNO
化学文摘社编号:
分子量:
179.23
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Concentration:
1.5 M in cyclohexane
Form:
liquid
InChI
1S/C6H14N.C4H8O.Li/c1-5(2)7-6(3)4;1-2-4-5-3-1;/h5-6H,1-4H3;1-4H2;/q-1;;+1
SMILES string
[Li+].C1CCOC1.CC(C)[N-]C(C)C
InChI key
YTJXGDYAEOTOCG-UHFFFAOYSA-N
vapor density
>1 (vs air)
form
liquid
concentration
1.5 M in cyclohexane
density
0.816 g/mL at 25 °C
storage temp.
2-8°C
Application
Lithium diisopropylamide mono(tetrahydrofuran) can be used:
- As an initiator in the anionic polymerization of D,L-lactide.
- In one of the key synthetic steps for the preparation of phenylacetic acid component of muscarinic M3 receptor antagonist.
- In the synthesis of new sexithiophene derivatives, which are used as electron donor materials in bilayer photovoltaic devices.
Other Notes
可能含少量 THF 和乙苯
signalword
Danger
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
target_organs
Central nervous system, hearing organs
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-0.4 °F - closed cup
flash_point_c
-18 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis and properties of end-capped sexithiophenes incorporating the ethylene dithiothiophene unit
Mason CR, et al.
Journal of Materials Chemistry, 15(14), 1446-1453 (2005)
Diastereoselective synthesis of the acid part of a new muscarinic M3 receptor antagonist
Mitsuya M, et al.
Tetrahedron, 56(51), 9901-9907 (2000)
Anionic polymerization of D, L-lactide initiated by lithium diisopropylamide
Bhaw-Luximon A, et al.
Polymer, 42(24), 9651-9656 (2001)
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