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Merck
CN

307467

顺式-1,2-环己二胺

97%

别名:

顺-1,2-环己二胺

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关于此项目

线性分子式:
C6H10(NH2)2
化学文摘社编号:
分子量:
114.19
PubChem Substance ID:
UNSPSC Code:
12352100
Beilstein/REAXYS Number:
2801644
MDL number:
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SMILES string

N[C@@H]1CCCC[C@@H]1N

InChI

1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2/t5-,6+

InChI key

SSJXIUAHEKJCMH-OLQVQODUSA-N

vapor pressure

0.4 mmHg ( 20 °C)

assay

97%

form

liquid

bp

92-93 °C/18 mmHg (lit.)

density

0.952 g/mL at 25 °C (lit.)

General description

cis-1,2-Diaminocyclohexane perturbed the spectrum of free pyrroloquinoline quinone (PQQ), a covalently linked form of which is the carbonyl cofactor of lysyl oxidase and also induced similar changes in the spectrum of lysyl oxidase.

Application

用于合成多齿配体,此类配体用于铀酰和过渡金属的络合。

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

158.0 °F - closed cup

flash_point_c

70 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The Journal of Organic Chemistry, 56, 6083-6083 (1991)
S N Gacheru et al.
The Journal of biological chemistry, 264(22), 12963-12969 (1989-08-05)
The observation that aliphatic diamines become poor substrates as the carbon chain length decreases and that ethylenediamine, the shortest diamine, is an irreversible inhibitor of lysyl oxidase led to the investigation of the mechanism of inhibition by ethylenediamine. The cis
The Journal of Organic Chemistry, 56, 3339-3339 (1991)
Y Kidani et al.
Journal of medicinal chemistry, 21(12), 1315-1318 (1978-12-01)
Platinum complexes derived from three isomers of 1,2-diaminocyclohexane have been synthesized and their antitumor activities were evaluated against ascites Sarcoma-180. All the platinum complexes had high antitumor activity. Platinum complexes derived from cis-1,2-diaminocyclohexane were more effective than those derived from
Hidekazu Yamada et al.
Journal of the American Chemical Society, 134(17), 7250-7253 (2012-04-18)
Optically active amidine dimer strands having a variety of chiral and achiral linkers with different stereostructures are synthesized and used as templates for diastereoselective imine-bond formations between two achiral carboxylic acid monomers bearing a terminal aldehyde group and racemic 1,2-cyclohexanediamine

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