308579
5,6-苯并-4,7,13,16,21,24-六氧杂-1,10-二氮杂二环[8.8.8]二十六碳-5-烯 溶液
50 wt. % in toluene
别名:
Kryptofix® 222B, Kryptand 222B
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关于此项目
经验公式(希尔记法):
C22H36N2O6
化学文摘社编号:
分子量:
424.53
Beilstein:
586455
EC 号:
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
表单
liquid
质量水平
浓度
50 wt. % in toluene
折射率
n20/D 1.516
密度
0.995 g/mL at 25 °C
官能团
ether
SMILES字符串
C1COCCN2CCOCCOCCN(CCO1)CCOc3ccccc3OCC2
InChI
1S/C22H36N2O6/c1-2-4-22-21(3-1)29-15-9-23-5-11-25-17-19-27-13-7-24(10-16-30-22)8-14-28-20-18-26-12-6-23/h1-4H,5-20H2
InChI key
QXLUTPDNMOEWGG-UHFFFAOYSA-N
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应用
5,6-Benzo-4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacos-5-ene can be used as a model ligand:
- In the metal-ligand complex formation studies to predict ligand coordination with metal ions (Eu & Gd) using magnetic resonance imaging (MRI) technique.
- In the study of coordination environment as well as redox and electronic properties of its YbII complexes.
法律信息
Kryptofix is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语:
Danger
危险分类
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
靶器官
Central nervous system, Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
46.4 °F - closed cup
闪点(°C)
8 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
危险化学品
易制毒化学品(3类)
此项目有
Screening of ligands for redox-active europium using magnetic resonance imaging
Corbin BA, et al.
Bioorganic & Medicinal Chemistry, 26(19), 5274-5279 (2018)
Spectroscopic and Electrochemical Trends in Divalent Lanthanides through Modulation of Coordination Environment
Jenks TC, et al.
Inorganic Chemistry, 59(4), 2613-2620 (2020)
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