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Merck
CN

310298

(R)-(+)-氧化苯乙烯

98%

别名:

(R)-(+)-环氧乙基苯, (R)-环氧苯乙烷

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关于此项目

经验公式(希尔记法):
C8H8O
化学文摘社编号:
分子量:
120.15
PubChem Substance ID:
UNSPSC Code:
12352005
Beilstein/REAXYS Number:
1984
MDL number:
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assay

98%

optical activity

[α]18/D +33°, neat

optical purity

ee: 95% (HPLC)

autoignition temp.

928 °F

expl. lim.

~22 %

refractive index

n20/D 1.534 (lit.)

bp

89-90 °C/23 mmHg (lit.)

density

1.051 g/mL at 25 °C (lit.)

SMILES string

C1O[C@@H]1c2ccccc2

InChI

1S/C8H8O/c1-2-4-7(5-3-1)8-6-9-8/h1-5,8H,6H2/t8-/m0/s1

InChI key

AWMVMTVKBNGEAK-QMMMGPOBSA-N



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Daniel Kuhn et al.
Journal of industrial microbiology & biotechnology, 39(8), 1125-1133 (2012-04-25)
Selection of the ideal microbe is crucial for whole-cell biotransformations, especially if the target reaction intensively interacts with host cell functions. Asymmetric styrene epoxidation is an example of a reaction which is strongly dependent on the host cell owing to
Michael Kotik et al.
Journal of biotechnology, 156(1), 1-10 (2011-08-23)
We performed a laboratory evolution study with the epoxide hydrolase from Aspergillus niger M200. This enzyme exhibits no enantioconvergence with the substrates styrene oxide or para-chlorostyrene oxide, i.e. racemic vicinal diols are produced from the racemic substrates. After saturation mutagenesis
Rainer Gross et al.
Biotechnology and bioengineering, 110(2), 424-436 (2012-08-14)
This study evaluates the technical feasibility of biofilm-based biotransformations at an industrial scale by theoretically designing a process employing membrane fiber modules as being used in the chemical industry and compares the respective process parameters to classical stirred-tank studies. To