(1S,2R)-(+)-去甲麻黄素

Name: (1<I>S</I>,2<I>R</I>)-(+)-去甲麻黄素
Brand: ALDRICH

98%

别名:

(1S,2R)-2-氨基-1-苯基-1-丙醇, D-(+)-去甲麻黄素, 苯丙醇胺, 赤型-α-(1-氨基乙基)苄醇

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所有图片(2)

About This Item

线性分子式:

C₆H₅CH(OH)CH(CH₃)NH₂

CAS Number:

37577-28-9

分子量:

151.21

Beilstein:

2802896

MDL编号:

MFCD00064411

UNSPSC代码:

12352116

PubChem化学物质编号:

24859081

NACRES:

NA.22

描述

Drug Control: Pszichotróp anyag / Psychotropic Substance (Hungary), 78/2022. (XII. 28.) BM rendelet

质量水平

200

方案

98%

表单

solid

旋光性

[α]20/D +40°, c = 7 in 1 M HCl

drug control

Pszichotróp anyag / Psychotropic Substance (Hungary), 78/2022. (XII. 28.) BM rendelet

mp

51-54 °C (lit.)

官能团

amine
hydroxyl
phenyl

储存温度

2-8°C

SMILES字符串

C[C@@H](N)[C@@H](O)c1ccccc1

InChI

1S/C9H13NO/c1-7(10)9(11)8-5-3-2-4-6-8/h2-7,9,11H,10H2,1H3/t7-,9-/m1/s1

InChI key

DLNKOYKMWOXYQA-VXNVDRBHSA-N

一般描述

(1S,2R)-(+)-Norephedrine is an enantiomer of ephedrine mainly used as a chiral auxiliary for asymmetric synthesis.

应用

(1S,2R)-(+)-Norephedrine may be used in the preparation of dendritic ligands, which on combining with Ru(II) complexes form efficient asymmetric transfer hydrogenation catalysts. It may also be used in the preparation of N-((1S,2R)-1-hydroxy-1-phenylpropan-2-yl)furan-2-carboxamide. This chiral amide can efficiently catalyze the enantioselective ethylation of aromatic and heteroaromatic aldehydes to secondary alcohols in the absence of titanium tetraisopropoxide as promotor.