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Merck
CN

323497

5,10,15,20-四(1-甲基-4-吡啶基)卟啉四(对甲苯磺酸盐)

Dye content 90 %

别名:

TMPyP, 内消旋-四(N-甲基-4-吡啶基)卟吩 四甲苯磺酸盐

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关于此项目

经验公式(希尔记法):
C72H66N8O12S4
化学文摘社编号:
分子量:
1363.60
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
6049195
Form:
powder
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form

powder

composition

Dye content, 90%

solubility

water: soluble 50 mM(lit.)

λmax

421 nm

SMILES string

Cc1ccc(cc1)S([O-])(=O)=O.Cc2ccc(cc2)S([O-])(=O)=O.Cc3ccc(cc3)S([O-])(=O)=O.Cc4ccc(cc4)S([O-])(=O)=O.C[n+]5ccc(cc5)-c6c7ccc(n7)c(-c8cc[n+](C)cc8)c9ccc([nH]9)c(-c%10cc[n+](C)cc%10)c%11ccc(n%11)c(-c%12cc[n+](C)cc%12)c%13ccc6[nH]%13

InChI

1S/C44H37N8.4C7H8O3S/c1-49-21-13-29(14-22-49)41-33-5-7-35(45-33)42(30-15-23-50(2)24-16-30)37-9-11-39(47-37)44(32-19-27-52(4)28-20-32)40-12-10-38(48-40)43(36-8-6-34(41)46-36)31-17-25-51(3)26-18-31;4*1-6-2-4-7(5-3-6)11(8,9)10/h5-28H,1-4H3,(H,45,46,47,48);4*2-5H,1H3,(H,8,9,10)/q+3;;;;/p-3/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;;;;

InChI key

AKZFRMNXBLFDNN-GVHKZQBISA-K

General description

5,10,15,20-四(1-甲基-4-吡啶基)卟啉四( 甲苯磺酸盐)(TMPyP),是一种带正电荷的双光子染料,可以与细胞培养物中的DNA结合并影响细胞活力。据报道,通过长期包封TMPyP纳米颗粒,可防止染料与细胞直接接触,但染料仍可在暴露于红外光时通过产生单线态氧而杀死细胞。 通过水热多元醇工艺可制备TMPyP官能化石墨烯负载的铂纳米颗粒催化剂。据报道,TMPyP与白色念珠菌(Candida albicans)一起孵育时,表现出出色的¹O2发光信号。通过光激发,TMPyP能够与化学还原的石墨烯氧化物发生电荷转移相互作用。据报道,它也是一种很有前景的光动力疗法光敏剂。

Application

5,10,15,20-四(1-甲基-4-吡啶基)卟啉四(甲苯磺酸盐)(TMPyP),是一种阳离子卟啉,用于研究石墨烯与阳离子卟啉通过UV-vis和荧光方法发生的非共价官能化。TMPyP可用作制备多功能膜的光学指示剂配体,用于视觉警告以及增强水溶液中镉离子的吸附去除。TMPyP还被用于从非共价吸附复合材料制备(TMPyP)-单壁碳纳米管(SWNT)/叶绿素铜钠-SWNT逐层组装复合膜。


存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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全球贸易项目编号

货号GTIN
323497-250MG04061826708736
323497-100MG04061833279380