324124
2-氯-1,3,2-苯并二氧磷杂环己烷-4-酮
95%, solid
别名:
SalPCl, Salicyl chlorophosphite
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关于此项目
经验公式（希尔记法）:
C7H4ClO3P
化学文摘社编号:
分子量:
202.53
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Beilstein/REAXYS Number:
1311951
产品名称
2-氯-1,3,2-苯并二氧磷杂环己烷-4-酮, 95%
Quality Level
assay
95%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
bp
127-128 °C/11 mmHg (lit.)
mp
36-40 °C (lit.)
functional group
phosphine
storage temp.
2-8°C
SMILES string
ClP1OC(=O)c2ccccc2O1
InChI
1S/C7H4ClO3P/c8-12-10-6-4-2-1-3-5(6)7(9)11-12/h1-4H
InChI key
BVOITXUNGDUXRW-UHFFFAOYSA-N
Application
2-氯-1,3,2-苯并二氧磷杂环己烷-4-酮可以下用途试剂：
- 醇的磷酸化和磷酰化。
- H-膦酸酯形成，常用于合成核苷酸。
- 合成三磷酸核苷，经由酰基保护的核苷处理。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Byun, H.-S.; Erukulla, R. K.; Bittman, R.
The Journal of Organic Chemistry, 59, 6495-6495 (1994)
Jacek Stawinski et al.
Accounts of chemical research, 35(11), 952-960 (2002-11-20)
The biological importance and practical significance of phosphate esters and their analogues have been the major driving forces for research in various areas of synthetic organic phosphorus chemistry. In this Account, the authors' studies on the development of a comprehensive
2-Chloro-4H-1, 3, 2-benzodioxaphosphorin-4-one
Ranganathan K
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 324124-5G | 04061833509463 |
| 324124-25G | 04061833509456 |