324124
2-氯-1,3,2-苯并二氧磷杂环己烷-4-酮
95%, solid
别名:
SalPCl, Salicyl chlorophosphite
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关于此项目
经验公式（希尔记法）:
C7H4ClO3P
化学文摘社编号:
分子量:
202.53
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Beilstein/REAXYS Number:
1311951
产品名称
2-氯-1,3,2-苯并二氧磷杂环己烷-4-酮, 95%
Quality Segment
assay
95%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
bp
127-128 °C/11 mmHg (lit.)
mp
36-40 °C (lit.)
functional group
phosphine
storage temp.
2-8°C
SMILES string
ClP1OC(=O)c2ccccc2O1
InChI
1S/C7H4ClO3P/c8-12-10-6-4-2-1-3-5(6)7(9)11-12/h1-4H
InChI key
BVOITXUNGDUXRW-UHFFFAOYSA-N
Application
2-氯-1,3,2-苯并二氧磷杂环己烷-4-酮可以下用途试剂：
- 醇的磷酸化和磷酰化。
- H-膦酸酯形成，常用于合成核苷酸。
- 合成三磷酸核苷，经由酰基保护的核苷处理。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges