325058
(S)-(+)-3-溴-2-甲基-1-丙醇
97%
别名:
(2S)-3-Bromo-2-methyl-1-propanol, (S)-3-Bromo-2-methylpropan-1-ol, (S)-3-Hydroxy-2-methylpropyl bromide
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关于此项目
线性分子式:
BrCH2CH(CH3)CH2OH
化学文摘社编号:
分子量:
153.02
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4738280
Assay:
97%
Form:
liquid
assay
97%
form
liquid
optical activity
[α]25/D +7.3°, c = 2 in chloroform
refractive index
n20/D 1.483 (lit.)
density
1.461 g/mL at 25 °C (lit.)
functional group
bromo, hydroxyl
SMILES string
C[C@@H](CO)CBr
InChI
1S/C4H9BrO/c1-4(2-5)3-6/h4,6H,2-3H2,1H3/t4-/m1/s1
InChI key
KIBOHRIGZMLNNS-SCSAIBSYSA-N
Application
(S)-(+)-3-Bromo-2-methyl-1-propanol is a precursor to synthesize the phase II mexiletine metabolite, (R)-mexiletine N-carbonyloxy-β-D-glucuronide. It can be used in the synthesis of (R)-(+)-muscopyridine, polycavernoside A and (+)-allopumiliotoxin 323B′. It can also be employed in building homochiral porous molecular networks.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
197.6 °F - closed cup
flash_point_c
92 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Total synthesis of the marine toxin polycavernoside A via selective macrolactonization of a trihydroxy carboxylic acid.
White J d, et al.
Journal of the American Chemical Society, 123(35), 8593-8595 (2001)
The Synthesis of (+)?Allopumiliotoxin 323B?.
Tan CH and Holmes A B
Chemistry?A European Journal , 7(9), 1845-1854 (2001)
First synthesis and full characterization of mexiletine N-carbonyloxy ?-D-glucuronide.
Cavalluzzi M M, et al.
Tetrahedron Letters, 51(40), 5265-5268 (2010)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 325058-1G | 04061837719202 |