32596
焦碳酸二烯丙基酯
≥95.0% (T)
别名:
(Alloc)2O, 二烯丙基焦碳酸酯
登录查看公司和协议定价
选择尺寸
关于此项目
线性分子式:
(CH2=CHCH2OCO)2O
化学文摘社编号:
分子量:
186.16
Beilstein:
4390381
MDL编号:
UNSPSC代码:
12352108
PubChem化学物质编号:
方案
≥95.0% (T)
折射率
n20/D 1.434 (lit.)
n20/D 1.434
沸点
60 °C/0.05 mmHg (lit.)
密度
1.121 g/mL at 25 °C (lit.)
应用
peptide synthesis
储存温度
2-8°C
SMILES字符串
C=CCOC(=O)OC(=O)OCC=C
InChI
1S/C8H10O5/c1-3-5-11-7(9)13-8(10)12-6-4-2/h3-4H,1-2,5-6H2
InChI key
XVSSGIXTKVRGAR-UHFFFAOYSA-N
正在寻找类似产品? 访问 产品对比指南
一般描述
Diallyl pyrocarbonate or (Alloc)2O is used as a reagent for the introduction of allyloxycarbonyl (Alloc or Aloc) protecting group to primary and secondary amines. In peptide synthesis, it is also used to protect amino acid functional groups due to its stability to the acidic and basic conditions. Various amino functional groups such as amino sugars and nucleosides are also protected by using diallyldicarbonate reagent.
其他说明
便于引入 N-烯丙氧基羰基 (N-Alloc) 氨基保护的试剂；烯丙基氨基甲酸酯保护易受钯(0)试剂裂解。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
201.2 °F - closed cup
闪点(°C)
94 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Diallyl dicarbonate. A convenient reagent for the synthesis of allyl carbamates.
Barcelo G, et al.
Tetrahedron Letters, 28(47), 5809-5810 (1987)
N-[(Allyloxycarbonyl) oxy] maleimide-styrene Copolymer
N Carmen, et al.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-2 (2001)
H. Kunz et al.
Angewandte Chemie (International Edition in English), 96, 426-426 (1984)
G. Sennyey et al.
Tetrahedron Letters, 28, 5809-5809 (1987)
O. Dangles et al.
The Journal of Organic Chemistry, 52, 4984-4984 (1987)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持