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Merck
CN

326712

Sigma-Aldrich

钌黑

greener alternative

别名:

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关于此项目

经验公式(希尔记法):
Ru
CAS Number:
分子量:
101.07
EC 号:
MDL编号:
UNSPSC代码:
12141739
PubChem化学物质编号:
NACRES:
NA.23
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方案

≥98%

质量水平

表单

powder

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

电阻率

7.1 μΩ-cm, 0°C

表面积

17-26 m2/g

沸点

3900 °C (lit.)

mp

2310 °C (lit.)

密度

12.45 g/cm3 (lit.)

环保替代产品分类

SMILES字符串

[Ru]

InChI

1S/Ru

InChI key

KJTLSVCANCCWHF-UHFFFAOYSA-N

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一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

应用

Ru based complexes may be used in the synthesis of anticancer drugs. Ru complexes in conjunction with magnesium may be used in the atom transfer radical addition (ATRA) and cyclization (ATRC) reactions.
Ru may be used as a catalyst in the following reactions;
  • oxidative coupling of indoles and pyrroles with several alkenes
  • arylations reactions.

包装

Packaged in glass bottles

储存分类代码

4.1B - Flammable solid hazardous materials

WGK

nwg

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Lipeng Wu et al.
Journal of the American Chemical Society, 135(10), 3989-3996 (2013-02-20)
An efficient and regioselective ruthenium-catalyzed hydroaminomethlyation of olefins is reported. Key to success is the use of specific 2-phosphino-substituted imidazole ligands and triruthenium dodecacarbonyl as catalyst. Both industrially important aliphatic as well as various functionalized olefins react with primary and
Rafael E Rodríguez-Lugo et al.
Nature chemistry, 5(4), 342-347 (2013-03-21)
The development of an efficient catalytic process that mimics the enzymatic function of alcohol dehydrogenase is critical for using biomass alcohols for both the production of H2 as a chemical energy carrier and fine chemicals under waste-free conditions. Dehydrogenation of
Bin Li et al.
The Journal of organic chemistry, 78(18), 9345-9353 (2013-09-13)
An efficient ruthenium-catalyzed oxidative coupling of indoles and pyrroles with various alkenes at the C2-position assisted by employing the N,N-dimethylcarbamoyl moiety as a directing group is reported. The catalytic reaction proceeds in an excellent regio- and stereoselective manner.
Direct synthesis of pyrroles by dehydrogenative coupling of β-aminoalcohols with secondary alcohols catalyzed by ruthenium pincer complexes.
Dipankar Srimani et al.
Angewandte Chemie (International ed. in English), 52(14), 4012-4015 (2013-03-08)
Mette T Petersen et al.
Organic letters, 15(8), 1986-1989 (2013-04-05)
A series of 5-substituted 2-pyrrolidinones was synthesized through a one-pot ruthenium alkylidene-catalyzed tandem RCM/isomerization/nucleophilic addition sequence. The intermediates resulting from RCM/isomerization showed reactivity toward electrophiles in aldol condensation reactions which provided a new entry for the total synthesis of the

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