328456
3-甲氧基苯酚
96%
别名:
3-羟基苯甲醚, 间苯二酚单甲醚
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关于此项目
线性分子式:
CH3OC6H4OH
化学文摘社编号:
分子量:
124.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-754-6
Beilstein/REAXYS Number:
1209898
MDL number:
产品名称
3-甲氧基苯酚, 96%
InChI key
ASHGTJPOSUFTGB-UHFFFAOYSA-N
InChI
1S/C7H8O2/c1-9-7-4-2-3-6(8)5-7/h2-5,8H,1H3
SMILES string
COc1cccc(O)c1
assay
96%
form
liquid
refractive index
n20/D 1.552 (lit.)
bp
113-115 °C/5 mmHg (lit.)
density
1.131 g/mL at 25 °C (lit.)
Quality Level
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Application
3-甲氧基苯酚用于合成：
- C (4) 对称杯 [4] 间苯二酚
- 2-亚硝基-5-甲氧基苯酚
- 6-甲氧基-2 (3 H )-苯并恶唑酮
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
233.6 °F - closed cup
flash_point_c
112 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Mario C Foti et al.
The Journal of organic chemistry, 73(6), 2408-2411 (2008-02-26)
The m-methoxy group is normally electron-withdrawing (EW), sigma(m) = +0.12, sigma(m+) = +0.05. The strong EW activity of a phenoxyl radical's O* atom causes the m-methoxy group to become electron-donating (ED), sigma(m)(+) = -0.14. In valence bond terms, this can
Alejandro Cordero Vargas et al.
Organic letters, 5(20), 3717-3719 (2003-09-26)
[reaction: see text] A short synthesis of (+/-)-10-norparvulenone and (+/-)-O-methylasparvenone was developed starting from commercially available m-methoxyphenol, hinging on a xanthate-mediated addition-cyclization sequence for the construction of the alpha-tetralone subunit.
L G Fenoll et al.
Biophysical chemistry, 84(1), 65-76 (2000-03-21)
Tyrosinase hydroxylates 3-hydroxyanisole in the 4-position. The reaction product accumulates in the reaction medium with a lag time (tau) which diminishes with increasing concentrations of enzyme and lengthens with increasing concentrations of substrate, thus fulfilling all the predictions of the
Majid Y Moridani et al.
Chemico-biological interactions, 142(3), 317-333 (2002-11-28)
A tyrosinase-directed therapeutic approach for malignant melanoma therapy uses the depigmenting phenolic agents such as 4-hydroxyanisole (4-HA) to form cytotoxic o-quinones. However, renal and hepatic toxicity was reported as side effects in a recent 4-HA clinical trial. In search of
McIldowie et al.
Organic letters, 2(24), 3869-3871 (2000-12-02)
The Lewis acid catalyzed condensation of 3-methoxyphenol with octanal produced the C(4) symmetric calix[4]resorcinarene 2, in high yield. Of the numerous stereo- and regioisomers possible, the rccc isomer with C(4) symmetry was the only product isolated (as a racemate). The
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