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Merck
CN

331872

(2R,3S)-(-)-N-Z-6-氧-2,3-二苯基吗啉

98%

别名:

(2R,3S)-(-)-6-氧代-2,3-二苯基-4-吗啉羧酸苄酯

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关于此项目

经验公式（希尔记法）:
C24H21NO4
化学文摘社编号:
100516-54-9
分子量:
387.43
NACRES:
NA.22
PubChem Substance ID:
24860004
UNSPSC Code:
12352005
MDL number:
MFCD00074958
Assay:
98%
Form:
solid

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产品名称

(2R,3S)-(-)-N-Z-6-氧-2,3-二苯基吗啉, 98%

InChI

1S/C24H21NO4/c26-21-16-25(24(27)28-17-18-10-4-1-5-11-18)22(19-12-6-2-7-13-19)23(29-21)20-14-8-3-9-15-20/h1-15,22-23H,16-17H2/t22-,23+/m0/s1

SMILES string

O=C1CN([C@H]([C@H](O1)c2ccccc2)c3ccccc3)C(=O)OCc4ccccc4

InChI key

HECRUWTZAMPQOS-XZOQPEGZSA-N

assay

98%

form

solid

optical activity

[α]25/D −66°, c = 5.5 in methylene chloride

mp

205-207 °C (lit.)

functional group

ester
phenyl

storage temp.

2-8°C

Application

(2R,3S)-(−)-N-Z-6-oxo-2,3-diphenylmorpholine is a Williams chiral auxiliary, which can be used:
  • As a template in the preparation of Fmoc-L-cyclopentylglycine, which acts as an angiotensin II antagonist.
  • In the synthesis of (L)-Fmoc-α-Me-Lys(Boc)-OH, a building block for the synthesis of peptidomimetics.
  • To introduce chirality in the modified amino acid named N-Fmoc 4-(2′-(di-tert-butylmalonyl))-l-phenylalanine.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBD3072V
MKBD3072
13518KR
10407LO
10107LC

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Enantioselective synthesis of (L)-Fmoc-alpha-Me-Lys (Boc)-OH via diastereoselective alkylation of oxazinone as a chiral auxiliary
Chauhan SS
Tetrahedron Letters, 50(49), 6913-6915 (2009)
Stereoselective preparation of L-4-(2′-malonyl) phenylalanine suitably protected for Fmoc-based synthesis of potent signal transduction inhibitory ligands
Gao Y and Burke Jr TR
Synlett, 2000(01), 134-136 (2000)
An efficient asymmetric synthesis of Fmoc-L-cyclopentylglycine via diastereoselective alkylation of glycine enolate equivalent
Singh S and Pennington MW
Tetrahedron Letters, 44(13), 2683-2685 (2003)

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