(2R,3S)-(-)-N-Z-6-氧-2,3-二苯基吗啉

Name: (2R,3S)-(-)-N-Z-6-氧-2,3-二苯基吗啉
Brand: ALDRICH

98%

别名:

(2R,3S)-(-)-6-氧代-2,3-二苯基-4-吗啉羧酸苄酯

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About This Item

经验公式（希尔记法）:

C₂₄H₂₁NO₄

CAS Number:

100516-54-9

分子量:

387.43

MDL编号:

MFCD00074958

UNSPSC代码:

12352005

PubChem化学物质编号:

24860004

NACRES:

NA.22

主要文件

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方案

98%

表单

solid

旋光性

[α]25/D −66°, c = 5.5 in methylene chloride

mp

205-207 °C (lit.)

官能团

ester
phenyl

储存温度

2-8°C

SMILES字符串

O=C1CN([C@H]([C@H](O1)c2ccccc2)c3ccccc3)C(=O)OCc4ccccc4

InChI

1S/C24H21NO4/c26-21-16-25(24(27)28-17-18-10-4-1-5-11-18)22(19-12-6-2-7-13-19)23(29-21)20-14-8-3-9-15-20/h1-15,22-23H,16-17H2/t22-,23+/m0/s1

InChI key

HECRUWTZAMPQOS-XZOQPEGZSA-N

应用

(2R,3S)-(−)-N-Z-6-oxo-2,3-diphenylmorpholine is a Williams chiral auxiliary, which can be used:

As a template in the preparation of Fmoc-L-cyclopentylglycine, which acts as an angiotensin II antagonist.
In the synthesis of (L)-Fmoc-α-Me-Lys(Boc)-OH, a building block for the synthesis of peptidomimetics.
To introduce chirality in the modified amino acid named N-Fmoc 4-(2′-(di-tert-butylmalonyl))-l-phenylalanine.