332062
二氯二(三丁基膦)镍(II)
别名:
NSC 54233
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关于此项目
线性分子式:
{[CH3(CH2)3]3P}2NiCl2
化学文摘社编号:
分子量:
534.23
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
InChI
1S/2C12H27P.2ClH.Ni/c2*1-4-7-10-13(11-8-5-2)12-9-6-3;;;/h2*4-12H2,1-3H3;2*1H;/q;;;;+2/p-2
SMILES string
Cl[Ni]Cl.CCCCP(CCCC)CCCC.CCCCP(CCCC)CCCC
InChI key
KPFOFXWYYUNJOZ-UHFFFAOYSA-L
reaction suitability
core: nickel
reagent type: catalyst
mp
43-45 °C (lit.)
storage temp.
2-8°C
Application
Catalyst for:
- Wenkert arylations
- Regioselective [2+2+2] cycloadditions
- Polymerization reactions
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
法规信息
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Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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