332844
4-甲氧基环己烷羧酸，顺式和反式的混合物
97%
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关于此项目
线性分子式:
CH3OC6H10CO2H
化学文摘社编号:
分子量:
158.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
liquid
InChI
1S/C8H14O3/c1-11-7-4-2-6(3-5-7)8(9)10/h6-7H,2-5H2,1H3,(H,9,10)
SMILES string
COC1CCC(CC1)C(O)=O
InChI key
WKILSRYNRQGRMA-UHFFFAOYSA-N
assay
97%
form
liquid
refractive index
n20/D 1.4687 (lit.)
functional group
carboxylic acid, ether
General description
cis-4-Methoxycyclohexanecarboxylic acid reacts with methyllithium to afford ketone, cis-4-methoxy-1-acetylcyclohexane. Reaction of cis-4-methoxycyclohexanecarboxylic acid with acetic acid and catalytic amount of sulphuric acid has been investigated.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Notes-Studies of Configuration. VI. cis-and trans-4-Methoxycyclohexanol.
Noyce DS and Weingarten HI.
The Journal of Organic Chemistry, 25(2), 260-262 (1960)
Studies of Configuration. IV. The Rearrangement of Methoxycyclohexanecarboxylic Acids with Acetic Anhydride1.
Noyce DS and Weingarten HI.
Journal of the American Chemical Society, 79(12), 3098-3102 (1957)
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