InChI
1S/C7H6FNO3/c1-12-7-3-2-5(9(10)11)4-6(7)8/h2-4H,1H3
SMILES string
COc1ccc(cc1F)[N+]([O-])=O
InChI key
XGMVTXUXZUPGGY-UHFFFAOYSA-N
assay
98%
mp
103-105 °C (lit.)
General description
2-Fluoro-4-nitroanisole is a 2-halo-4-nitroanisole and its photoreaction with the nucleophiles hydroxide ion and pyridine has been investigated. Mechanism of photoreaction of 2-fluoro-4-nitroanisole with n-hexylamine has been investigated.
Application
2-Fluoro-4-nitroanisole was employed as alternative biochemical photoprobe for proteins.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Gene G Wubbels et al.
The Journal of organic chemistry, 73(5), 1925-1934 (2008-01-25)
Photoreactions of 4-nitroanisole and the 2-halo-4-nitroanisoles (halogen = F, Cl, Br, and I) with the nucleophiles hydroxide ion and pyridine have been investigated quantitatively to extend the findings recently communicated for cyanide ion. The halonitroanisoles on excitation form triplet pi,pi*
The photosubstitution of 2-fluoro-4-nitroanisole with n-hexylamine. Evidence of two different triplet excited states in a dual mechanistic pathway.
Pleixats R and Marquet J.
Tetrahedron, 46(4), 1343-1352 (1990)
The Search for Biochemical Photoprobes. III. The Photoreactions of 4-Nitroveratrole and 2-Fluoro-4-nitroanisole with Bovine Pancreatic Ribonuclease A and with Model Nucleophiles.
Marquet J, et al.
Tetrahedron, 49(6), 1297-1306 (1993)
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