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335304

(S)-(+)-4-异丙基-3-丙酰基-2-噁唑烷酮

Name: (<I>S</I>)-(+)-4-异丙基-3-丙酰基-2-噁唑烷酮
Brand: ALDRICH

98%

别名:

(S)-3-丙酰基-4-异丙基-2-噁唑烷酮

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关于此项目

经验公式（希尔记法）:

C₉H₁₅NO₃

化学文摘社编号:

77877-19-1

分子量:

185.22

UNSPSC Code:

12352005

NACRES:

NA.22

PubChem Substance ID:

24860302

MDL number:

MFCD00043401

Beilstein/REAXYS Number:

3542849

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属性

assay

98%

form

liquid

optical activity

[α]25/D +93°, c = 8.7 in methylene chloride

refractive index

n20/D 1.464 (lit.)

bp

102-106 °C/0.75 mmHg (lit.)

density

1.094 g/mL at 25 °C (lit.)

SMILES string

CCC(=O)N1[C@H](COC1=O)C(C)C

InChI

1S/C9H15NO3/c1-4-8(11)10-7(6(2)3)5-13-9(10)12/h6-7H,4-5H2,1-3H3/t7-/m1/s1

InChI key

HOWPHXVPNNPSAZ-SSDOTTSWSA-N

说明

Application

(S)-(+)-4-Isopropyl-3-propionyl-2-oxazolidinone can be used as a building block to prepare:

(25S)-cholestenoic-26-acid, a potent ligand for the hormonal DAF-12 receptor in Caenorhabditis elegans
doliculide

Other Notes

Versatile chiral auxiliary for asymmetric synthesis. For a recent review, see Aldrichimica Acta .

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Preparation and biological activity of 24-epi-26,26,26,27,27,27-hexafluoro- 1 alpha,25-dihydroxyvitamin D2.

K Iseki et al.

Chemical & pharmaceutical bulletin, 43(11), 1897-1901 (1995-11-01)

A new fluorinated analog of vitamin D2, 24-epi-26,26,26,27,27,27-hexafluoro- 1 alpha,25-dihydroxyvitamin D2, was efficiently synthesized starting from (R)-4-isopropyl-3-propionyl-2- oxazolidinone with high stereochemical control. In all four physiological test systems, the fluorinate vitamin D2 analog was found to be slightly less active

Stereoselective synthesis of the hormonally active (25 S)-δ7-dafachronic acid,(25 S)-δ4-dafachronic acid,(25 S)-dafachronic acid, and (25 S)-cholestenoic acid.

Martin R, et al.

Organic & Biomolecular Chemistry, 6(23), 4293-4295 (2008)

Enantioselective total synthesis of doliculide, a potent cytotoxic cyclodepsipeptide of marine origin and structure-cytotoxicity relationships of synthetic doliculide congeners

Hiroyuki I, et al.

Tetrahedron, 50(45), 12853-12882 (1994)

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货号	GTIN
335304-1G	04061838097712