337501
[三(二甲基苯基膦)](2,5-降冰片二烯)六氟磷酸铑(I)
97%
别名:
[(2,3-η)-Bicyclo[2.2.1]hepta-2,5-diene]tris(dimethylphenylphosphine)rhodium(I) hexafluorophosphate
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选择尺寸
关于此项目
经验公式（希尔记法）:
C31H41F6P4Rh
化学文摘社编号:
分子量:
754.45
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
InChI
1S/3C8H11P.C7H8.F6P.Rh/c3*1-9(2)8-6-4-3-5-7-8;1-2-7-4-3-6(1)5-7;1-7(2,3,4,5)6;/h3*3-7H,1-2H3;1-4,6-7H,5H2;;/q;;;;-1;+1
SMILES string
[Rh+].F[P-](F)(F)(F)(F)F.[CH]1[CH]C2[CH][CH]C1C2.CP(C)c3ccccc3.CP(C)c4ccccc4.CP(C)c5ccccc5
InChI key
KSBHDOZWEREXLG-UHFFFAOYSA-N
assay
97%
reaction suitability
core: rhodium, reagent type: catalyst
mp
158-161 °C (lit.)
Application
Catalyst for aminomethylation
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Gaspard Huber et al.
Magnetic resonance in chemistry : MRC, 56(7), 672-678 (2017-12-09)
Cryptophanes, cage-molecules constituted of aromatic bowls, are now well recognised as powerful xenon hosts in 129 Xe NMR-based biosensing. In the quest of a dual probe that can be addressed only by NMR, we have studied three cryptophanes bearing a
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