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Merck
CN

337528

烯丙基溴

reagent grade, 97%, contains ≤1000 ppm propylene oxide as stabilizer

别名:

3-溴-1-丙烯

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关于此项目

线性分子式:
CH2=CHCH2Br
化学文摘社编号:
分子量:
120.98
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-446-6
Beilstein/REAXYS Number:
605308
MDL number:
Assay:
97%
Form:
liquid
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InChI key

BHELZAPQIKSEDF-UHFFFAOYSA-N

InChI

1S/C3H5Br/c1-2-3-4/h2H,1,3H2

SMILES string

BrCC=C

grade

reagent grade

vapor density

4.2 (vs air)

assay

97%

form

liquid

autoignition temp.

554 °F

contains

≤1000 ppm propylene oxide as stabilizer

expl. lim.

7.3 %

Quality Level

bp

70-71 °C (lit.)

mp

−119 °C (lit.)

density

1.398 g/mL at 25 °C (lit.)

functional group

alkyl halide, bromo

storage temp.

2-8°C

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Application

使用烯丙基溴:
  • 通过Suzuki型偶联反应合成立体定向烯丙基化芳烃。
  • 应用于醛和酮的Barbier型烯丙基反应。{17]
  • 合成一个单体,1-1-(烯丙氧基)-4-硝基苯,同时合成纳米结构分子印迹聚合物,用于在生物和药物样品中选择性色氨酸的测定。

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

30.2 °F - closed cup

flash_point_c

-1 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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A tryptophan assay based on the glassy carbon electrode modified with a nano-sized tryptophan-imprinted polymer and multi-walled carbon nanotubes
Alizadeh T and Amjadi S
New. J. Chem., 41(11), 4493-4502 (2017)
Catalyst-Free Suzuki-Type Coupling of Allylic Bromides with Arylboronic Acids
Scrivanti A, et al.
European Journal of Organic Chemistry, 2012(2), 264-268 (2012)
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Chemical communications (Cambridge, England), 47(20), 5843-5845 (2011-04-20)
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Chemical communications (Cambridge, England), (40)(40), 4209-4211 (2006-10-13)
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Design and synthesis of modular oxazoline ligands for the enantioselective chromium-catalyzed addition of allyl bromide to ketones.
Jeremie J Miller et al.
Journal of the American Chemical Society, 129(10), 2752-2753 (2007-02-21)

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