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337528

烯丙基溴

reagent grade, 97%, contains ≤1000 ppm propylene oxide as stabilizer

别名:

3-溴-1-丙烯

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关于此项目

线性分子式:
CH2=CHCH2Br
化学文摘社编号:
106-95-6
分子量:
120.98
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
24860486
EC Number:
203-446-6
Beilstein/REAXYS Number:
605308
MDL number:
MFCD00000244
Assay:
97%
Form:
liquid
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grade

reagent grade

Quality Level

200

vapor density

4.2 (vs air)

assay

97%

form

liquid

autoignition temp.

554 °F

contains

≤1000 ppm propylene oxide as stabilizer

expl. lim.

7.3 %

refractive index

n20/D 1.469 (lit.)

bp

70-71 °C (lit.)

mp

−119 °C (lit.)

density

1.398 g/mL at 25 °C (lit.)

functional group

alkyl halide, bromo

storage temp.

2-8°C

SMILES string

BrCC=C

InChI

1S/C3H5Br/c1-2-3-4/h2H,1,3H2

InChI key

BHELZAPQIKSEDF-UHFFFAOYSA-N

Application

使用烯丙基溴：
  • 通过Suzuki型偶联反应合成立体定向烯丙基化芳烃。
  • 应用于醛和酮的Barbier型烯丙基反应。{17]
  • 合成一个单体，1-1-（烯丙氧基）-4-硝基苯，同时合成纳米结构分子印迹聚合物，用于在生物和药物样品中选择性色氨酸的测定。

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Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B

存储类别

3 - Flammable liquids

flash_point_f

30.2 °F - closed cup

flash_point_c

-1 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB7660
SDBB6571
STBK7835
SDBB5344
SDBB2968

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A tryptophan assay based on the glassy carbon electrode modified with a nano-sized tryptophan-imprinted polymer and multi-walled carbon nanotubes
Alizadeh T and Amjadi S
New. J. Chem., 41(11), 4493-4502 (2017)
Catalyst-Free Suzuki-Type Coupling of Allylic Bromides with Arylboronic Acids
Scrivanti A, et al.
European Journal of Organic Chemistry, 2012(2), 264-268 (2012)
Kiew-Ching Lee et al.
Chemical communications (Cambridge, England), (40)(40), 4209-4211 (2006-10-13)
The total synthesis of natural (4R,5R)-antillatoxin and its analog (4S,5S)-antillatoxin has been achieved; the optically pure key intermediates were prepared from indium mediated allylation of either primary or secondary allylic bromide with aldehyde in aquoues media, followed by highly selective
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全球贸易项目编号

货号GTIN
337528-1L04061826743607
337528-250ML04061826743614