339938
3,4-二氨基甲苯
99%, purified by sublimation
别名:
4-甲基-邻-苯二胺, 3,4-甲苯二胺
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关于此项目
线性分子式:
CH3C6H3(NH2)2
化学文摘社编号:
分子量:
122.17
EC Number:
207-826-2
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
507965
MDL number:
Assay:
99%
assay
99%
purified by
sublimation
bp
155-156 °C/18 mmHg (lit.)
mp
87-89 °C (lit.)
SMILES string
Cc1ccc(N)c(N)c1
InChI
1S/C7H10N2/c1-5-2-3-6(8)7(9)4-5/h2-4H,8-9H2,1H3
InChI key
DGRGLKZMKWPMOH-UHFFFAOYSA-N
General description
3,4-Diaminotoluene on treatment with [{PhP(Se)(μ-Se)}2], causes the rupture of the dimer, giving PhP(Se)(NHC6H3(CH3-3)NH-1,2).
Application
3,4-Diaminotoluene was employed as catalyst for the two-step reduction of Zn(II) ions at dropping mercury electrode in 1M NaClO4 + 0.001M HClO4. It was also used in the synthesis of new benzimidazole derivatives with cyclohexylalkyl and aralkyl substituents in position 2.
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signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Bridge cleavage of [{PhP(Se)(?-Se)}2] by 1,2- C6H4(EH)(E'H) (E, E'=O or NH). X-ray crystal structure of PhP(Se)(NHC6H4NH-1,2).
Bhattacharyya P, et al.
Journal of Organometallic Chemistry, 623(1), 116-119 (2001)
The catalysis of the reduction of Zn (II) ions by 3, 4-diaminotoluene.
Dalmata G.
Electrochimica Acta, 42(9), 1307-1314 (1997)
Synthesis and tuberculostatic activity of new benzimidazole derivatives.
Foks H, et al.
Chemistry of Heterocyclic Compounds, 42(5), 611-614 (2006)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 339938-1G | 04061825770871 |