343560
二异丙基(乙氧基羰甲基)磷酸酯
95%
别名:
Ethyl (diisopropyl phosphono)acetate
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关于此项目
线性分子式:
C2H5O2CCH2P(O)[OCH(CH3)2]2
化学文摘社编号:
分子量:
252.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352108
MDL number:
Assay:
95%
Form:
liquid
InChI
1S/C10H21O5P/c1-6-13-10(11)7-16(12,14-8(2)3)15-9(4)5/h8-9H,6-7H2,1-5H3
SMILES string
CCOC(=O)CP(=O)(OC(C)C)OC(C)C
InChI key
YZEWJYIDAAGEHA-UHFFFAOYSA-N
assay
95%
form
liquid
reaction suitability
reaction type: C-C Bond Formation
refractive index
n20/D 1.427 (lit.)
bp
142-143 °C/11 mmHg (lit.)
density
1.06 g/mL at 25 °C (lit.)
Application
Reactant for:
- Preparation of spiroimine ring fragment of spirolides via stereoselective intermolecular Diels-Alder and aza-Wittig cyclization
- Katsuki-Sharpless epoxidation reaction
- Preparation of nine-membered diallylic sulfonamides as chiral building blocks
- Alpha-phosphono lactams for subsequent Wadsworth-Emmons olefination, and Suzuki coupling reactions to yield diverse pyrrolidinone compounds
- Synthesis of galactosylceramide analog that induces Th1-biased responses in human (NKT) cells
- Stereoselective total synthesis of the ionophore antibiotic zincophorin (M144255)
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
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