343641
( R )-(+)-香茅醛
technical grade
别名:
(+)-香茅醛, (3R)-3,7-二甲基-6-辛烯醛
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关于此项目
线性分子式:
(CH3)2C=CHCH2CH2CH(CH3)CH2CHO
化学文摘社编号:
分子量:
154.25
UNSPSC Code:
12352114
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-194-5
Beilstein/REAXYS Number:
1720791
MDL number:
Form:
liquid
InChI key
NEHNMFOYXAPHSD-SNVBAGLBSA-N
InChI
1S/C10H18O/c1-9(2)5-4-6-10(3)7-8-11/h5,8,10H,4,6-7H2,1-3H3/t10-/m1/s1
SMILES string
C[C@H](CC\C=C(\C)C)CC=O
grade
technical grade
form
liquid
refractive index
n20/D 1.448 (lit.)
bp
207 °C (lit.)
density
0.851 g/mL at 25 °C (lit.)
functional group
aldehyde
Quality Level
General description
(R)-(+)-香茅醛是一种单萜醛。这种手性有机物可作为有机合成砌块制备各种手性化合物。也可用作不对称反应的手性催化剂或配体。
Application
(R)-(+)-香茅醛可用作反应剂合成各种化合物，包括L-薄荷醇、caparratriene和含氧族元素的硝酮衍生物。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
167.0 °F - closed cup
flash_point_c
75 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Xiangxian Ying et al.
Molecules (Basel, Switzerland), 24(6) (2019-03-21)
The members of the Old Yellow Enzyme (OYE) family are capable of catalyzing the asymmetric reduction of (E/Z)-citral to (R)-citronellal-a key intermediate in the synthesis of L-menthol. The applications of OYE-mediated biotransformation are usually hampered by its insufficient enantioselectivity and
Walter S Leal et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(46), 18704-18709 (2013-10-30)
The southern house mosquito, Culex quinquefasciatus, has one of the most acute and eclectic olfactory systems of all mosquito species hitherto studied. Here, we used Illumina sequencing to identify olfactory genes expressed predominantly in antenna, mosquito's main olfactory organ. Less
M S Melo et al.
Pharmaceutical biology, 48(4), 411-416 (2010-07-22)
Citronellal is a monoterpene reported to be a major component of the essential oils in various aromatic species of plants. The present study evaluated the central nervous system depressant and antinociceptive properties of citronellal through behavioral experimental models. Following intraperitoneal
Lucindo José Quintans-Júnior et al.
Journal of orofacial pain, 24(3), 305-312 (2010-07-29)
To evaluate the antinociceptive effects of citronellal (CTL) on formalin-, capsaicin-, and glutamate-induced orofacial nociception in mice and to investigate whether such effects might involve a change in neural excitability. Male mice were pretreated with CTL (50, 100, and 200
Lucindo Quintans-Júnior et al.
Journal of medicinal food, 14(6), 630-639 (2011-04-13)
Citronellal (CT) is a monoterpenoid and the major constituent of the mixture of terpenoids that give the citronella oil its lemon scent. Citronella oil is widely used around the world for various purposes and is mainly obtained from plants of
实验方案
-β-Farnesene; α-Huµlene; Germacrene D; (+)-Valencene; Bicyclogermacrene; (+)-δ-Cadinene
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