346217
(R)-(+)-1-(2-萘基)乙醇
98%
别名:
(R)-(+)-α-甲基-2-萘甲醇
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关于此项目
线性分子式:
C10H7CH(CH3)OH
化学文摘社编号:
分子量:
172.22
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3195952
Assay:
98%
InChI
1S/C12H12O/c1-9(13)11-7-6-10-4-2-3-5-12(10)8-11/h2-9,13H,1H3/t9-/m1/s1
SMILES string
C[C@@H](O)c1ccc2ccccc2c1
InChI key
AXRKCRWZRKETCK-SECBINFHSA-N
assay
98%
optical activity
[α]20/D +38°, c = 5 in ethanol
mp
68-70 °C (lit.)
Gene Information
human ... UGT2B17(7367), UGT2B7(7364)
Application
(R)-(+)-1-(2-萘基)乙醇可在存在手性二齿钛路易斯酸催化剂的条件下，与 2-氯苯乙酮反应合成 (S)-2-氯-1-苯基乙醇。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Bidentate Lewis acids for organic synthesis.
Maruoka K.
Catalysis Today, 66(1), 33-45 (2001)
Ingo Bichlmaier et al.
Journal of medicinal chemistry, 49(5), 1818-1827 (2006-03-03)
A set of 28 enantiomers comprising rigid and flexible secondary alcohols was synthesized by the asymmetric Corey-Bakshi-Shibata reduction. The enantiomerically pure alcohols were subjected to enzymatic glucuronidation assays employing the human UDP-glucuronosyltransferases (UGTs) 2B7 and 2B17. Both UGTs displayed high
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